Compounds Containing Nitrogen

280 Questions
2023 JEE Mains MCQ
JEE Main 2023 (Online) 13th April Morning Shift

In the reaction given below

JEE Main 2023 (Online) 13th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 76 English

'B' is

A.
JEE Main 2023 (Online) 13th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 76 English Option 1
B.
JEE Main 2023 (Online) 13th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 76 English Option 2
C.
JEE Main 2023 (Online) 13th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 76 English Option 3
D.
JEE Main 2023 (Online) 13th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 76 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 12th April Morning Shift

The incorrect statement regarding the reaction given below is

JEE Main 2023 (Online) 12th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 75 English

A.
'$\mathrm{B}$' is N-nitroso ammonium compound
B.
The product '$\mathrm{B}$' formed in the above reaction is $\mathrm{p}$-nitroso compound at low temperature
C.
The electrophile involved in the reaction is $\mathrm{NO}^{+}$
D.
The reaction occurs at low temperature
2023 JEE Mains MCQ
JEE Main 2023 (Online) 11th April Morning Shift

JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 74 English

'X' is

A.
JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 74 English Option 1
B.
JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 74 English Option 2
C.
JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 74 English Option 3
D.
JEE Main 2023 (Online) 11th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 74 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 10th April Evening Shift

The major product 'P' formed in the given reaction is:

JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 73 English

A.
JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 73 English Option 1
B.
JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 73 English Option 2
C.
JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 73 English Option 3
D.
JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 73 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 10th April Evening Shift

In the reaction given below:

JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 72 English

The product 'X' is:

A.
JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 72 English Option 1
B.
JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 72 English Option 2
C.
JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 72 English Option 3
D.
JEE Main 2023 (Online) 10th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 72 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 10th April Morning Shift

Isomeric amines with molecular formula C$_8$H$_{11}$N give the following tests

Isomer (P) $\Rightarrow$ Can be prepared by Gabriel phthalimide synthesis

Isomer (Q) $\Rightarrow$ Reacts with Hinsberg's reagent to give solid insoluble in NaOH

Isomer (R) $\Rightarrow$ Reacts with HONO followed by $\beta$-naphthol in NaOH to give red dye.

Isomers (P), (Q) and (R) respectively are

A.
JEE Main 2023 (Online) 10th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 71 English Option 1
B.
JEE Main 2023 (Online) 10th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 71 English Option 2
C.
JEE Main 2023 (Online) 10th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 71 English Option 3
D.
JEE Main 2023 (Online) 10th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 71 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 8th April Evening Shift

The product ($\mathrm{P}$) formed from the following multistep reaction is:

JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 70 English

A.
JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 70 English Option 1
B.
JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 70 English Option 2
C.
JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 70 English Option 3
D.
JEE Main 2023 (Online) 8th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 70 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 8th April Morning Shift

Match List I with List II:

JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 69 English 1

LIST I (Reagent) LIST II (Product)
A. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 69 English 2 I. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 69 English 3
B. $\mathrm{HBF_4,\Delta}$ II. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 69 English 4
C. $\mathrm{Cu,HCl}$ III. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 69 English 5
D. $\mathrm{CuCN/KCN}$ IV. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 69 English 6

Choose the correct answer from the options given below:

A.
A-III, B-I, C-IV, D-II
B.
A-III, B-I, C-II, D-IV
C.
A-IV, B-III, C-II, D-I
D.
A-I, B-III, C-IV, D-II
2023 JEE Mains MCQ
JEE Main 2023 (Online) 6th April Morning Shift

The major products A and B from the following reactions are:

JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 67 English

A.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 67 English Option 1
B.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 67 English Option 2
C.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 67 English Option 3
D.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 67 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 6th April Morning Shift

The major product formed in the following reaction is

JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 66 English

A.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 66 English Option 1
B.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 66 English Option 2
C.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 66 English Option 3
D.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 66 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 6th April Morning Shift

JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 68 English

Compound $\mathrm{P}$ is neutral, $\mathrm{Q}$ gives effervescence with $\mathrm{NaHCO}_{3}$ while $\mathrm{R}$ reacts with Hinsbergs reagent to give solid soluble in $\mathrm{NaOH}$. Compound $\mathrm{P}$ is

A.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 68 English Option 1
B.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 68 English Option 2
C.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 68 English Option 3
D.
JEE Main 2023 (Online) 6th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 68 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 1st February Morning Shift

In the following reaction, 'A' is

JEE Main 2023 (Online) 1st February Morning Shift Chemistry - Compounds Containing Nitrogen Question 95 English

A.
JEE Main 2023 (Online) 1st February Morning Shift Chemistry - Compounds Containing Nitrogen Question 95 English Option 1
B.
JEE Main 2023 (Online) 1st February Morning Shift Chemistry - Compounds Containing Nitrogen Question 95 English Option 2
C.
JEE Main 2023 (Online) 1st February Morning Shift Chemistry - Compounds Containing Nitrogen Question 95 English Option 3
D.
JEE Main 2023 (Online) 1st February Morning Shift Chemistry - Compounds Containing Nitrogen Question 95 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 31st January Evening Shift
An organic compound $[\mathrm{A}]\left(\mathrm{C}_{4} \mathrm{H}_{11} \mathrm{~N}\right)$, shows optical activity and gives $\mathrm{N}_{2}$ gas on treatment with $\mathrm{HNO}_{2}$. The compound $[\mathrm{A}]$ reacts with $\mathrm{PhSO}_{2} \mathrm{Cl}$ producing a compound which is soluble in $\mathrm{KOH}$. The structure of $\mathrm{A}$ is :
A.
JEE Main 2023 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 96 English Option 1
B.
JEE Main 2023 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 96 English Option 2
C.
JEE Main 2023 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 96 English Option 3
D.
JEE Main 2023 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 96 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 31st January Morning Shift

JEE Main 2023 (Online) 31st January Morning Shift Chemistry - Compounds Containing Nitrogen Question 93 English

Consider the above reaction and identify the product B.

A.
JEE Main 2023 (Online) 31st January Morning Shift Chemistry - Compounds Containing Nitrogen Question 93 English Option 1
B.
JEE Main 2023 (Online) 31st January Morning Shift Chemistry - Compounds Containing Nitrogen Question 93 English Option 2
C.
JEE Main 2023 (Online) 31st January Morning Shift Chemistry - Compounds Containing Nitrogen Question 93 English Option 3
D.
JEE Main 2023 (Online) 31st January Morning Shift Chemistry - Compounds Containing Nitrogen Question 93 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 30th January Evening Shift
The most stable carbocation for the following is:

JEE Main 2023 (Online) 30th January Evening Shift Chemistry - Compounds Containing Nitrogen Question 92 English
A.
b
B.
d
C.
c
D.
a
2023 JEE Mains MCQ
JEE Main 2023 (Online) 30th January Evening Shift

JEE Main 2023 (Online) 30th January Evening Shift Chemistry - Compounds Containing Nitrogen Question 91 English

In the above conversion of compound $(\mathrm{X})$ to product $(\mathrm{Y})$, the sequence of reagents to be used will be:

A.
$\begin{array}{lll}\text { (i) } \mathrm{Br}_2, \mathrm{Fe} & \text { (ii) } \mathrm{Fe}, \mathrm{H}^{+} & \text {(iii) } \mathrm{LiAIH}_4\end{array}$
B.
$\begin{array}{lll}\text { (i) } \mathrm{Br}_2(\mathrm{aq}) & \text { (ii) } \mathrm{LiAIH}_4 & \text { (iii) } \mathrm{H}_3 \mathrm{O}^{+}\end{array}$
C.
(i) $\mathrm{Fe}, \mathrm{H}^{+}$   (ii) $\mathrm{Br}_2$ (aq)   (iii) $\mathrm{HNO}_2$   (iv) $\mathrm{H}_3 \mathrm{PO}_2$
D.
(i) $\mathrm{Fe}, \mathrm{H}^{+}$   (ii) $\mathrm{Br}_2(\mathrm{aq})$   (iii) $\mathrm{HNO}_2$   (iv) $\mathrm{CuBr}$
2023 JEE Mains MCQ
JEE Main 2023 (Online) 30th January Morning Shift

Benzyl isocyanide can be obtained by :

A. JEE Main 2023 (Online) 30th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 90 English 1

B. JEE Main 2023 (Online) 30th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 90 English 2

C. JEE Main 2023 (Online) 30th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 90 English 3

D. JEE Main 2023 (Online) 30th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 90 English 4

Choose the correct answer from the options given below :

A.
B and C
B.
A and D
C.
A and B
D.
Only B
2023 JEE Mains MCQ
JEE Main 2023 (Online) 29th January Evening Shift

Reaction of propanamide with $\mathrm{Br_2/KOH(aq)}$ produces :

A.
Propanenitrile
B.
Propylamine
C.
Ethylnitrile
D.
Ethylamine
2023 JEE Mains MCQ
JEE Main 2023 (Online) 29th January Morning Shift

The major product 'P' for the following sequence of reactions is :

JEE Main 2023 (Online) 29th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 88 English

A.
JEE Main 2023 (Online) 29th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 88 English Option 1
B.
JEE Main 2023 (Online) 29th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 88 English Option 2
C.
JEE Main 2023 (Online) 29th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 88 English Option 3
D.
JEE Main 2023 (Online) 29th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 88 English Option 4
2023 JEE Mains MCQ
JEE Main 2023 (Online) 29th January Morning Shift

Match List I with List II

List I List II
Reaction Reagents
(A) Hoffmann Degradation (I) $\mathrm{Conc. KOH}$, $\Delta$
(B) Clemenson reduction (II) $\mathrm{CHCl_3,NaOH/H_3O}$$^ \oplus $
(C) Cannizaro reaction (III) $\mathrm{Br_2,NaOH}$
(D) Reimer-Tiemann Reaction (IV) $\mathrm{Zn-Hg/HCl}$

Choose the correct answer from the options given below :

A.
(A) - III, (B) - IV, (C) - I, (D) - II
B.
(A) - II, (B) - IV, (C) - I, (D) - III
C.
(A) - III, (B) - IV, (C) - II, (D) - I
D.
(A) - II, (B) - I, (C) - III, (D) - IV
2023 JEE Mains MCQ
JEE Main 2023 (Online) 25th January Evening Shift

Match List I with List II

List I (Amines) List II ($\mathrm{pK_b}$)
A. Aniline I. 3.25
B. Ethanamine II. 3.00
C. N-Ethylethanamine III. 9.38
D. N, N-Diethylethanamine IV. 3.29

Choose the correct answer from the options given below :

A.
A-III, B-II, C-I, D-IV
B.
A-III, B-II, C-IV, D-I
C.
A-III, B-IV, C-II, D-I
D.
A-I, B-IV, C-II, D-III
2023 JEE Mains MCQ
JEE Main 2023 (Online) 25th January Evening Shift

Match List I with List II

List I
Isomeric pairs
List II
Type of isomers
A. Propanamine and N-Methylethanamine I. Metamers
B. Hexan-2-one and Hexan-3-one II. Positional isomers
C. Ethanamide and Hydroxyethanimine III. Functional isomers
D. o-nitrophenol and p-nitrophenol IV. Tautomers

Choose the correct answer from the options given below :

A.
A-III, B-I, C-IV, D-II
B.
A-III, B-IV, C-I, D-II
C.
A-II, B-III, C-I, D-IV
D.
A-IV, B-III, C-I, D-II
2023 JEE Mains MCQ
JEE Main 2023 (Online) 24th January Evening Shift

Given below are two statements :

JEE Main 2023 (Online) 24th January Evening Shift Chemistry - Compounds Containing Nitrogen Question 82 English 1

JEE Main 2023 (Online) 24th January Evening Shift Chemistry - Compounds Containing Nitrogen Question 82 English 2

In the light of the above statements, choose the correct answer from the options given below:

A.
Both Statement I and Statement II are true
B.
Statement I is false but Statement II is true
C.
Statement I is true but Statement II is false
D.
Both Statement I and Statement II are false
2023 JEE Mains MCQ
JEE Main 2023 (Online) 24th January Evening Shift

Choose the correct colour of the product for the following reaction.

JEE Main 2023 (Online) 24th January Evening Shift Chemistry - Compounds Containing Nitrogen Question 83 English

A.
White
B.
Yellow
C.
Red
D.
Blue
2023 JEE Mains MCQ
JEE Main 2023 (Online) 24th January Evening Shift

Given below are two statements:

Statement I : Pure Aniline and other arylamines are usually colourless.

Statement II : Arylamines get coloured on storage due to atmospheric reduction.

In the light of the above statements, choose the most appropriate answer from the options given below :

A.
Both Statement I and Statement II are correct
B.
Statement I is correct but Statement II is incorrect
C.
Both Statement I and Statement II are incorrect
D.
Statement I is incorrect but Statement I is correct
2023 JEE Mains MCQ
JEE Main 2023 (Online) 24th January Morning Shift

Increasing order of stability of the resonance structures is :

JEE Main 2023 (Online) 24th January Morning Shift Chemistry - Compounds Containing Nitrogen Question 81 English

Choose the correct answer from the options given below :

A.
D, C, B, A
B.
C, D, B, A
C.
C, A, B, D
D.
D, C, A, B
2022 JEE Mains MCQ
JEE Main 2022 (Online) 29th July Evening Shift

The Hinsberg reagent is

A.
JEE Main 2022 (Online) 29th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 97 English Option 1
B.
JEE Main 2022 (Online) 29th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 97 English Option 2
C.
JEE Main 2022 (Online) 29th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 97 English Option 3
D.
JEE Main 2022 (Online) 29th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 97 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 29th July Morning Shift

Which among the following is the strongest Bronsted base?

A.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 100 English Option 1
B.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 100 English Option 2
C.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 100 English Option 3
D.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 100 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 29th July Morning Shift

JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 99 English

Consider the above reaction, the compound 'A' is :

A.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 99 English Option 1
B.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 99 English Option 2
C.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 99 English Option 3
D.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 99 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 29th July Morning Shift

JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 98 English

Which among the following represent reagent 'A'?

A.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 98 English Option 1
B.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 98 English Option 2
C.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 98 English Option 3
D.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 98 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 29th July Morning Shift

Consider the following reaction sequence:

JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 101 English

The product 'B' is :

A.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 101 English Option 1
B.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 101 English Option 2
C.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 101 English Option 3
D.
JEE Main 2022 (Online) 29th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 101 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 28th July Evening Shift

Given below are two statements: one is labelled as Assertion $\mathbf{A}$ and the other is labelled as Reason $\mathbf{R}$

Assertion A : Aniline on nitration yields ortho, meta & para nitro derivatives of aniline.

Reason $\mathrm{R}$ : Nitrating mixture is a strong acidic mixture.

In the light of the above statements, choose the correct answer from the options given below

A.
Both A and R are true and R is the correct explanation of A
B.
Both $\mathrm{A}$ and $\mathrm{R}$ are true but $\mathrm{R}$ is NOT the correct explanation of $\mathrm{A}$
C.
A is true but R is false
D.
A is false but R is true
2022 JEE Mains MCQ
JEE Main 2022 (Online) 28th July Morning Shift

Identify the correct statement for the below given transformation.

JEE Main 2022 (Online) 28th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 103 English

A.
$\mathrm{A}-\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CH}-\mathrm{CH}_{3}, \mathrm{~B}-\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CH}_{2}$, Saytzeff products
B.
$\mathrm{A}-\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CH}-\mathrm{CH}_{3}$, B $-\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CH}_{2}$, Hofmann products
C.
$\mathrm{A}-\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CH}_{2}, \mathrm{~B}-\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CHCH}_{3}$, Hofmann products
D.
$\mathrm{A}-\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CH}_{2}, \mathrm{~B}-\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}=\mathrm{CHCH}_{3}$, Saytzeff products
2022 JEE Mains MCQ
JEE Main 2022 (Online) 27th July Evening Shift

An organic compound $'\mathrm{A}'$ contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound $'\mathrm{A}'$ with standard base indicates that the molecular weight of $'\mathrm{A}'$ is $131 \pm 2$. When a sample of $'\mathrm{A}'$ is treated with aq. $\mathrm{NaOH}$, a liquid separates which contains $\mathrm{N}$ but not $\mathrm{Cl}$. Treatment of the obtained liquid with nitrous acid followed by phenol gives orange precipitate. The compound $'\mathrm{A}'$ is :

A.
JEE Main 2022 (Online) 27th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 104 English Option 1
B.
JEE Main 2022 (Online) 27th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 104 English Option 2
C.
JEE Main 2022 (Online) 27th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 104 English Option 3
D.
JEE Main 2022 (Online) 27th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 104 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 27th July Morning Shift

Match List I with List II.

List I List II
(A) Benzenesulphonyl chloride (I) Test for primary amines
(B) Hoffmann bromamide reaction (II) Anti Saytzeff
(C) Carbylamine reaction (III) Hinsberg reagent
(D) Hoffmann orientation (IV) Known reaction of Isocyanates.

Choose the correct answer from the options given below:

A.
A-IV, B-III, C-II, D-I
B.
A-IV, B-II, C-I, D-III
C.
A-III, B-IV, C-I, D-II
D.
A-IV, B-III, C-I, D-II
2022 JEE Mains MCQ
JEE Main 2022 (Online) 26th July Evening Shift

The correct sequential order of the reagents for the given reaction is

JEE Main 2022 (Online) 26th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 106 English

A.
$\mathrm{HNO}_{2}, \mathrm{Fe} / \mathrm{H}^{+}, \mathrm{HNO}_{2}, \mathrm{KI}, \mathrm{H}_{2} \mathrm{O} / \mathrm{H}^{+}$
B.
$\mathrm{HNO}_{2}, \mathrm{KI}, \mathrm{Fe} / \mathrm{H}^{+}, \mathrm{HNO}_{2}, \mathrm{H}_{2} \mathrm{O} /$ warm
C.
$\mathrm{HNO}_{2}, \mathrm{KI}, \mathrm{HNO}_{2}, \mathrm{Fe} / \mathrm{H}^{+}, \mathrm{H}_{2} \mathrm{O} / \mathrm{H}^{+}$
D.
$\mathrm{HNO}_{2}, \mathrm{Fe} / \mathrm{H}^{+}, \mathrm{KI}, \mathrm{HNO}_{2}, \mathrm{H}_{2} \mathrm{O} /$ warm
2022 JEE Mains MCQ
JEE Main 2022 (Online) 26th July Morning Shift

The correct stability order of the following diazonium salt is

JEE Main 2022 (Online) 26th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 107 English

A.
$(\mathrm{A})>(\mathrm{B})>(\mathrm{C})>(\mathrm{D})$
B.
$(\mathrm{A})>(\mathrm{C})>(\mathrm{D})>(\mathrm{B})$
C.
$(\mathrm{C})>(\mathrm{A})>(\mathrm{D})>(\mathrm{B})$
D.
$(\mathrm{C})>(\mathrm{D})>(\mathrm{B})>(\mathrm{A})$
2022 JEE Mains MCQ
JEE Main 2022 (Online) 26th July Morning Shift

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Experimental reaction of $\mathrm{CH}_{3} \mathrm{Cl}$ with aniline and anhydrous $\mathrm{AlCl}_{3}$ does not give $o$ and $p$-methylaniline.

Reason (R): The $-\mathrm{NH}_{2}$ group of aniline becomes deactivating because of salt formation with anhydrous $\mathrm{AlCl}_{3}$ and hence yields $m$-methyl aniline as the product.

In the light of the above statements, choose the most appropriate answer from the options given below :

A.
Both A and R are true and (R) is the correct explanation of (A).
B.
Both A and R are true but (R) is not the correct explanation of (A).
C.
(A) is true, but (R) is false.
D.
(A) is false, but (R) is true.
2022 JEE Mains MCQ
JEE Main 2022 (Online) 25th July Morning Shift

An organic compound 'A' on reaction with NH3 followed by heating gives compound B. Which on further strong heating gives compound C (C8H5NO2). Compound C on sequential reaction with ethanolic KOH, alkyl chloride and hydrolysis with alkali gives a primary amine. The compound A is :

A.
JEE Main 2022 (Online) 25th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 109 English Option 1
B.
JEE Main 2022 (Online) 25th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 109 English Option 2
C.
JEE Main 2022 (Online) 25th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 109 English Option 3
D.
JEE Main 2022 (Online) 25th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 109 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 29th June Evening Shift

In Friedel-Crafts alkylation of aniline, one gets

A.
alkylated product with ortho and para substitution.
B.
secondary amine after acidic treatment.
C.
an amide product.
D.
positively charged nitrogen at benzene ring.
2022 JEE Mains MCQ
JEE Main 2022 (Online) 29th June Morning Shift

JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 125 English 1
JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 125 English 2

Consider the above reactions, the product A and product B respectively are

A.
JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 125 English Option 1
B.
JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 125 English Option 2
C.
JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 125 English Option 3
D.
JEE Main 2022 (Online) 29th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 125 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 28th June Evening Shift

With respect to the following reaction, consider the given statements :

JEE Main 2022 (Online) 28th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 123 English

(A) o-Nitroaniline and p-nitroaniline are the predominant products.

(B) p-Nitroaniline and m-nitroaniline are the predominant products.

(C) HNO3 acts as an acid.

(D) H2SO4 acts as an acid.

Choose the correct option.

A.
(A) and (C) are correct statements.
B.
(A) and (D) are correct statements.
C.
(B) and (D) are correct statements.
D.
(B) and (C) are correct statements.
2022 JEE Mains MCQ
JEE Main 2022 (Online) 28th June Morning Shift

Identify the major product formed in the following sequence of reactions:

JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 122 English

A.
JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 122 English Option 1
B.
JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 122 English Option 2
C.
JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 122 English Option 3
D.
JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 122 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 28th June Morning Shift

A primary aliphatic amine on reaction with nitrous acid in cold (273 K) and there after raising temperature of reaction mixture to room temperature (298 K), gives a/an

A.
nitrile
B.
alcohol
C.
diazonium salt
D.
secondary amine
2022 JEE Mains MCQ
JEE Main 2022 (Online) 27th June Evening Shift

Decarboxylation of all six possible forms of diaminobenzoic acids C6H3(NH2)2COOH yields three products A, B and C. Three acids give a product 'A', two acids gives a product 'B' and one acid give a product 'C'. The melting point of product 'C' is

A.
63$^\circ$C
B.
90$^\circ$C
C.
104$^\circ$C
D.
142$^\circ$C
2022 JEE Mains MCQ
JEE Main 2022 (Online) 27th June Morning Shift

Given below are two statements :

Statement I : In Hofmann degradation reaction, the migration of only an alkyl group takes place from carbonyl carbon of the amide to the nitrogen atom.

Statement II : The group is migrated in Hofmann degradation reaction to electron deficient atom.

In the light of the above statements, choose the most appropriate answer from the options given below :

A.
Both Statement I and Statement II are correct.
B.
Both Statement I and Statement II are incorrect.
C.
Statement I is correct but Statement II is incorrect.
D.
Statement I is incorrect but Statement II is correct.
2022 JEE Mains MCQ
JEE Main 2022 (Online) 26th June Evening Shift

Which statement is NOT correct for p-toluenesulphonyl chloride?

A.
It is known as Hinsberg's reagent.
B.
It is used to distinguish primary and secondary amines.
C.
On treatment with secondary amine, it leads to a product, that is soluble in alkali.
D.
It doesn't react with tertiary amines.
2022 JEE Mains MCQ
JEE Main 2022 (Online) 26th June Evening Shift

The final product 'C' in the following series of reactions

JEE Main 2022 (Online) 26th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 117 English

A.
JEE Main 2022 (Online) 26th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 117 English Option 1
B.
JEE Main 2022 (Online) 26th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 117 English Option 2
C.
JEE Main 2022 (Online) 26th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 117 English Option 3
D.
JEE Main 2022 (Online) 26th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 117 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 26th June Morning Shift

Among the following structures, which will show the most stable enamine formation? (Where Me is $-$CH3)

A.
JEE Main 2022 (Online) 26th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 118 English Option 1
B.
JEE Main 2022 (Online) 26th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 118 English Option 2
C.
JEE Main 2022 (Online) 26th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 118 English Option 3
D.
JEE Main 2022 (Online) 26th June Morning Shift Chemistry - Compounds Containing Nitrogen Question 118 English Option 4
2022 JEE Mains MCQ
JEE Main 2022 (Online) 25th June Evening Shift

Amongst the following, the major product of the given chemical reaction is

JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 114 English

A.
JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 114 English Option 1
B.
JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 114 English Option 2
C.
JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 114 English Option 3
D.
JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 114 English Option 4