Chemical Bonding and Molecular Structure
126 Questions
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2017
Q51
NEET
MSQ
10 Mar 2026
Which of the following pairs of compounds is isostructural ?
A.
Tel2, XeF2
B.
IBr2$-$, XeF2
C.
IF3, XeF2
D.
BeCl2, XeF2
2016
Q52
NEET
MCQ
10 Mar 2026
The hybridizations of atomic orbitals of nitrogen in NO$_2^ + $, NO$_3^ - $ and NH$_4^ + $ respectively are
A.
sp, sp3 and sp2
B.
sp2, sp3 and sp3
C.
sp, sp2 and sp3
D.
sp2, sp and sp3
2016
Q53
NEET
MCQ
10 Mar 2026
The correct geometry and hybridization for XeF4 are
A.
octahedral, sp3d2
B.
trigonal bipyramidal, sp3d
C.
planar triangle, sp3d3
D.
square planar, sp3d2
2016
Q54
NEET
MCQ
10 Mar 2026
Among the following, which one is a wrong statement ?
A.
PH5 and BiCl5 do not exist.
B.
p$\pi $-d$\pi $ bonds are present in SO2.
C.
SeF4 and CH4 have same shape.
D.
I3+ has bent geometry.
2016
Q55
NEET
MCQ
10 Mar 2026
Which one of the following compounds shows the presence of intramolecular hydrogen bond?
A.
H2O2
B.
HCN
C.
Cellulose
D.
Concentrated acetic acid
2016
Q56
NEET
MCQ
10 Mar 2026
Consider the molecules CH4, NH3 and H2O.
Which of the given statements is false?
Which of the given statements is false?
A.
The H $-$ O $-$ H bond angle in H2O is smaller than the H $-$ N $-$ H bond angle in NH3.
B.
The H $-$ C $-$ H bond angle in CH4 is larger than the H $-$ N $-$ H bond angle in NH3.
C.
The H $-$ C $-$ H bond angle in CH4, the H $-$ N $-$ H bond angle in NH3, and the H $-$ O $-$ H bond angle in H2O are all greater than 90o.
D.
The H $-$ O $-$ H bond angle in H2O is larger than the H $-$ C $-$ H bond angle in CH4.
2016
Q57
NEET
MCQ
10 Mar 2026
Predict the correct order among the following :
A.
bond pair - bond pair > long pair - bond pair > lone pair - lone pair
B.
lone pair - bond pair > bond pair - bond pair > lone pair - lone pair
C.
lone pair - lone pair > lone pair - bond pair > bond pair - bond pair
D.
lone pair - lone pair > bond pair - bond pair > lone pair - bond pair
2016
Q58
NEET
MCQ
10 Mar 2026
Which of the following pairs of ions is isoelectronic and isostructural ?
A.
$C{O_3}^{2 - },\,\,N{O_3}^ - $
B.
$C{lO_3}^{2 - },\,\,C{O_3}^{2 - }$
C.
$S{O_3}^{2 - },\,\,N{O_3}^ - $
D.
$Cl{O_3}^ - ,\,\,S{O_3}^{2 - }$
2015
Q59
NEET
MCQ
10 Mar 2026
In which of the following pairs, both the species are not isostructural ?
A.
Diamond, Silicon carbide
B.
NH3, PH3
C.
XeF4, XeO4
D.
SiCl4, PCl4+
2015
Q60
NEET
MCQ
10 Mar 2026
Decreasing order of stability of O2, O2$-$, O2+ and O22$-$ is
A.
O22$-$ > O2$-$ > O2 > O2+
B.
O2 > O2+ > O22$-$ > O2$-$
C.
O2$-$ > O22$-$ > O2+ > O2
D.
O2+ > O2 > O2$-$ > O22$-$
2015
Q61
NEET
MCQ
10 Mar 2026
The correct bond order in the following species is
A.
O2+ < O2$-$ < O22+
B.
O2$-$ < O2+ < O22+
C.
O22+ < O2+ < O2$-$
D.
O22+ < O2$-$ < O2+
2015
Q62
NEET
MCQ
10 Mar 2026
Maximum bond angle at nitrogen is present in which of the following ?
A.
NO2+
B.
NO3$-$
C.
NO2
D.
NO2$-$
2015
Q63
NEET
MCQ
10 Mar 2026
Which of the following species contains equal number of $\sigma $- and $\pi $-bonds ?
A.
(CN)2
B.
CH2(CN)2
C.
HCO3$-$
D.
XeO4
2015
Q64
NEET
MCQ
10 Mar 2026
Which of the following pairs of ions are isoelectronic and isostructural ?
A.
SO32$-$, NO3$-$
B.
ClO3$-$, SO32$-$
C.
CO32$-$, SO32$-$
D.
ClO3$-$, CO32$-$,
2015
Q65
NEET
MCQ
10 Mar 2026
Which of the following options represents the correct bond order ?
A.
O2$-$ > O2 < O2+
B.
O2$-$ < O2 > O2+
C.
O2$-$ > O2 > O2+
D.
O2$-$ < O2 < O2+
2014
Q66
NEET
MCQ
10 Mar 2026
Which of the following molecules has the maximum dipole moment ?
A.
CO2
B.
CH4
C.
NH3
D.
NF3
2014
Q67
NEET
MCQ
10 Mar 2026
Which one of the following species has plane triangular shape ?
A.
N3
B.
NO3$-$
C.
NO2$-$
D.
CO2
2013
Q68
NEET
MCQ
10 Mar 2026
The outer orbitals of C in ethane molecule can be considered to be hybridized to give three equivalent sp2 orbitals. The total number of sigma $\left( \sigma \right)$ and pi $\left( \pi \right)$ bonds in ethane molecule is
A.
3 sigma $\left( \sigma \right)$ and 2 pi $\left( \pi \right)$ bonds
B.
4 sigma $\left( \sigma \right)$ and 1 pi $\left( \pi \right)$ bonds
C.
5 sigma $\left( \sigma \right)$ and 1 pi $\left( \pi \right)$ bonds
D.
1 sigma $\left( \sigma \right)$ and 2 pi $\left( \pi \right)$ bonds
2013
Q69
NEET
MCQ
10 Mar 2026
In which of the following ionization processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic.
A.
O2 $ \to $ O2+
B.
C2 $ \to $ C2+
C.
NO $ \to $ NO+
D.
N2 $ \to $ N2+
2013
Q70
NEET
MCQ
10 Mar 2026
The pair of species that has the same bond order in the following is
A.
CO, NO+
B.
NO$-$, CN$-$
C.
O2, N2
D.
O2, B2
2013
Q71
NEET
MCQ
10 Mar 2026
In which of the following pair both the species have sp3 hybridization ?
A.
SiF4, BeH2
B.
NF3, H2O
C.
NF3, BF3
D.
H2S, BF3
2013
Q72
NEET
MCQ
10 Mar 2026
XeF2 is isostructural with
A.
SbCl3
B.
BaCl2
C.
TeF2
D.
ICl2$-$
2013
Q73
NEET
MCQ
10 Mar 2026
Dipole-induced dipole interactions are present in which of the following pairs
A.
HCl and He atoms
B.
SiF4 and He atoms
C.
H2O and alcohol
D.
Cl2 and CCl4
2013
Q74
NEET
MCQ
10 Mar 2026
Which of the following is electron-deficient ?
A.
(BH3)2
B.
PH3
C.
(CH3)2
D.
(SiH3)2
2013
Q75
NEET
MCQ
10 Mar 2026
Which of the following is a polar molecule?
A.
SiF4
B.
XeF4
C.
BF3
D.
SF4
2013
Q76
NEET
MCQ
10 Mar 2026
Which of the following is paramagnetic?
A.
CN$-$
B.
NO+
C.
CO
D.
O2$-$
2013
Q77
NEET
MCQ
10 Mar 2026
Identify the correct order of solubility in aqueous medium.
A.
Na2S > CuS > ZnS
B.
Na2S > ZnS > CuS
C.
Cus > ZnS > Na2S
D.
ZnS > Na2S > CuS
2012
Q78
NEET
MCQ
10 Mar 2026
Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them
A.
$NO < {O_2}^ - < {C_2}^{2 - } < He_2^ + $
B.
${O_2}^ - < NO < {C_2}^{2 - } < He_2^ + $
C.
${C_2}^{2 - } < He_2^ + < {O_2}^ - < NO$
D.
$He_2^ + < {O_2}^ - < NO < {C_2}^{2 - }$
2012
Q79
NEET
MCQ
10 Mar 2026
During change of O2 to O$_2^{ - }$ ion, the electron adds on which one of the following orbitals ?
A.
${\pi ^ * }$ orbital
B.
$\pi $ orbital
C.
${\sigma ^ * }$ orbital
D.
$\sigma $ orbital
2012
Q80
NEET
MCQ
10 Mar 2026
Which one of the following pairs is isostructural (i.e., having the same shape and hybridization) ?
A.
[BCl3 and BrCl3]
B.
[NH3 and NO$_3^ - $]
C.
[NF3 and BF3]
D.
[BF$_4^ - $ and NH$_4^ + $]
2012
Q81
NEET
MCQ
10 Mar 2026
Which of the following species contains three bond pairs and one lone pair arround the central atom ?
A.
H2O
B.
BF3
C.
NH2$-$
D.
PCl3
2012
Q82
NEET
MCQ
10 Mar 2026
The pair of species with the same bond order is
A.
O$_2^{2 - }$, B2
B.
O$_2^{ + }$, NO+
C.
NO, CO
D.
N2, O2
2012
Q83
NEET
MCQ
10 Mar 2026
Bond order of 1.5 is shown by
A.
O2+
B.
O2$-$
C.
O22$-$
D.
O2
2011
Q84
NEET
MCQ
10 Mar 2026
The pairs of species of oxygen and their
magnetic behaviours are noted below. Which of
the following presents the correct description?
A.
$O_2^ - ,O_2^{2 - }$ - Both diamagnetic
B.
$O_2^ + ,{O_2}$ - Both paramagnetic
C.
O, $O_{2}^{2-}$ - Both paramagnetic
D.
${O^ + },O_2^{2 - }$ - Both paramagnetic
2011
Q85
NEET
MCQ
10 Mar 2026
Which of the following structures is the most preferred and hence of lowest energy for SO3?
A.
B.
C.
D.
2011
Q86
NEET
MCQ
10 Mar 2026
Which of the two ions from the list given below that have the geometry that is explained by the same hybridization of orbitals, NO$_2^ - $. NO$_3^ - $, NH$_2^ - $, NH$_4^ + $, SCN$-$?
A.
NO$_2^ - $ and NO$_3^ - $
B.
NH$_4^ + $ and NO$_3^ - $
C.
SCN$-$ and NH$_2^ - $
D.
NO$_2^ - $ and NH$_2^ - $
2011
Q87
NEET
MCQ
10 Mar 2026
The pairs of species of oxygen and their magnetic behavior are noted below. Which of the following presents the correct description?
A.
O$_2^ - $, O$_2^{2 - }$ - Both diamagnetic
B.
O+, O$_2^{2 - }$ - Both paramagnetic
C.
O$_2^{ + }$, O2 - Both paramagnetic
D.
O, O$_2^{2 - }$ - Both paramagnetic
2011
Q88
NEET
MCQ
10 Mar 2026
The correct order of increasing bond length of C $-$ H, C $-$ O, C $-$ C and C$=$C is
A.
C $-$ H < C$=$C < C $-$ O < C $-$ C
B.
C $-$ C < C$=$C < C $-$ O < C $-$ H
C.
C $-$ O < C $-$ H < C $-$ C < C$=$C
D.
C $-$ H < C $-$ O < C $-$ C < C$=$C
2011
Q89
NEET
MCQ
10 Mar 2026
Which of the following has the minimum bond length ?
A.
O2+
B.
O2$-$
C.
O22$-$
D.
O2
2010
Q90
NEET
MCQ
10 Mar 2026
Some of the properties of the two species, $NO_3^ - $ and ${H_3}{O^ + }$ are described below. Which one of them is current?
A.
Dissimilar in hybridization for the central atom with different structures.
B.
Isostructural with same hybridization for the central atom.
C.
Isostructural with different hybridization for the central atom
D.
Similar in hybridization for the central atom with different structures.
2010
Q91
NEET
MCQ
10 Mar 2026
In which of the following molecules the central atom does not have sp3 hybridization?
A.
CH4
B.
SF4
C.
BF4$-$
D.
NH4+
2010
Q92
NEET
MCQ
10 Mar 2026
In which of the following pairs of molecules/ ions, the central atoms have sp2 hybridisation ?
A.
NO$_2^{ - }$ and NH3
B.
BF3 and NO$_2^{ - }$
C.
NH$_2^{ - }$ and H2O
D.
BF3 and NH$_2^{ - }$
2010
Q93
NEET
MCQ
10 Mar 2026
In which one of the following species the central atom has the type of hybridization which is not the same as that present in the other three ?
A.
SF4
B.
I3$-$
C.
SbCl52$-$
D.
PCl5
2010
Q94
NEET
MCQ
10 Mar 2026
Which one of the following species does not exist under normal conditions?
A.
Be2+
B.
Be2
C.
B2
D.
Li2
2009
Q95
NEET
MCQ
10 Mar 2026
According to MO theory which of the lists ranks the nitrogen species in terms of increasing bond order ?
A.
$N_2^{2 - } < N_2^ - < {N_2}$
B.
${N_2} < N_2^{2 - } < N_2^ - $
C.
$N_2^ - < N_2^{2 - } < {N_2}$
D.
$N_2^ - < {N_2} < N_2^{2 - }$
2009
Q96
NEET
MCQ
10 Mar 2026
In which of the following molecules/ions BF3, NO$_2^ - $, NH$_2^ - $ and H2O, the central atom is sp2 hybridised?
A.
NH$_2^ - $ and H2O
B.
NO$_2^ - $ and H2O
C.
BF3 and NO$_2^ - $
D.
NO$_2^ - $ and NH$_2^ - $
2009
Q97
NEET
MCQ
10 Mar 2026
What is the dominant intermolecular force or bond that must be overcome in converting liquid CH3OH to a gas?
A.
Dipole-dipole interaction
B.
Covalent bonds
C.
London dispersion force
D.
Hydrogen bonding
2008
Q98
NEET
MCQ
10 Mar 2026
The correct order of increasing bond angles in the following triatomic species is
A.
NO$_2^ + $ < NO2 < NO$_2^ - $
B.
NO$_2^ + $ < NO$_2^ - $ < NO2
C.
NO$_2^ - $ < NO$_2^ + $ < NO2
D.
NO$_2^ - $ < NO2 < NO$_2^ + $
2008
Q99
NEET
MCQ
10 Mar 2026
Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them
A.
$NO < {O_2}^ - < {C_2}^{2 - } < He_2^ + $
B.
${O_2}^ - < NO < {C_2}^{2 - } < He_2^ + $
C.
${C_2}^{2 - } < He_2^ + < {O_2}^ - < NO$
D.
$He_2^ + < {O_2}^ - < NO < {C_2}^{2 - }$
2007
Q100
NEET
MCQ
10 Mar 2026
The correct order of C $-$ O bond length among CO, CO${_3^{2 - }}$, CO2 is
A.
CO < CO${_3^{2 - }}$ < CO2
B.
CO${_3^{2 - }}$ < CO2 < CO
C.
CO < CO2 < CO${_3^{2 - }}$
D.
CO2 < CO${_3^{2 - }}$ < CO



has maximum number of covalent bonds.