2014
NEET
MCQ
AIPMT 2014
Which one is most reactive towards nucleophilic addition reaction?
A.
B.
C.
D.
2013
NEET
MCQ
NEET 2013
The order of stability of the following tautomeric compounds is


A.
II > I > III
B.
II > III > I
C.
I > II > III
D.
III > II > I
2013
NEET
MCQ
NEET 2013
Reaction by which benzaldehyde cannot be prepared
A.


B.


C.


D.


2012
NEET
MCQ
AIPMT 2012 Mains
Consider the reaction :
RCHO + NH2NH2 $ \to $ RCH $=$ N $-$ NH2
What sort of reaction is it?
RCHO + NH2NH2 $ \to $ RCH $=$ N $-$ NH2
What sort of reaction is it?
A.
Electrophilic addition-elimination reaction
B.
Free radical addition-elimination reaction
C.
Electrophilic substitution-elimination reaction
D.
Nucleophilic addition-elimination reaction
2012
NEET
MCQ
AIPMT 2012 Mains
Consider the following reaction
The product A is
The product A is
A.
C6H5CHO
B.
C6H5OH
C.
C6H5COCH3
D.
C6H5Cl
2012
NEET
MCQ
AIPMT 2012 Prelims
CH3CHO and C6H5CH2CHO can be distinguished chemically by
A.
Benedict's test
B.
Iodoform test
C.
Tollen's reagent test
D.
Fehling's solution test
2012
NEET
MCQ
AIPMT 2012 Prelims
Predict the products in the given reaction.
A.


B.


C.


D.


2012
NEET
MCQ
AIPMT 2012 Prelims
Acetone is treated with excess of ethanol in the presence of hydrochloric acid. The product obtained is
A.
B.
C.
D.
2012
NEET
MCQ
AIPMT 2012 Prelims
The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid (B), acetic acid (C) and formic acid (D) is
A.
B > A > D > C
B.
B > D > C > A
C.
A > B > C > D
D.
A > C > B > D
2012
NEET
MSQ
AIPMT 2012 Mains
Which of the following compounds will give a yellow precipitate with iodine and alkali?
A.
Acetophenone
B.
Methyl acetate
C.
Acetamide
D.
2-Hydroxypropane
2011
NEET
MCQ
AIPMT 2011 Mains
An organic compound A on treatment with NH3 gives B, which on heating gives C. C when treated with Br2 in the presence of KOH produces ethyl amine. Compound A is
A.
CH3COOH
B.
CH3CH2CH2COOH
C.
D.
CH3CH2COOH
2011
NEET
MCQ
AIPMT 2011 Mains
The order of reactivity of phenyl magnesium bromide (PhMgBr) with the following compounds:


A.
III > II > I
B.
II > I > III
C.
I > III > II
D.
I > II > III
2011
NEET
MCQ
AIPMT 2011 Mains
Match the compounds given in List-I with List-II and select the suitable option using the code given below.
| List-I |
List-II |
||
|---|---|---|---|
| (A) | Benzaldehyde | (i) | Phenolphthalein |
| (B) | Phthalic anhydride | (ii) | Benzoin condensation |
| (C) | Phenyl benzoate | (iii) | Oil of wintergreen |
| (D) | Methyl salicylate | (iv) | Fries rearrangement |
A.
(A)-(iv), (B)-(i), (C)-(iii), (D)-(ii)
B.
(A)-(iv), (B)-(ii), (C)-(iii), (D)-(i)
C.
(A)-(ii), (B)-(iii), (C)-(iv), (D)-(i)
D.
(A)-(ii), (B)-(i), (C)-(iv), (D)-(iii)
2011
NEET
MCQ
AIPMT 2011 Prelims
Clemmensen reduction of a ketone is carried out in the presence of which of the following?
A.
Glycol with KOH
B.
Zn-Hg with HCl
C.
LiAlH4
D.
H2 and Pt as catalyst
2011
NEET
MCQ
AIPMT 2011 Prelims
In a set of reactions m-bromobenzoic acid gave a product D. Identify the product D.


A.
B.
C.
D.
2011
NEET
MCQ
AIPMT 2011 Prelims
Which one is a nucleophilic substitution reaction among the following ?
A.


B.


C.


D.


2010
NEET
MCQ
AIPMT 2010 Mains
Which one of the following compounds will be most readily dehydrated?
A.
B.
C.
D.
2010
NEET
MCQ
AIPMT 2010 Prelims
Which of the following reactions will not result in the formation of carbon-carbon bonds?
A.
Reimer-Tiemann reaction
B.
Cannizzaro reaction
C.
Wurtz reaction
D.
Friedel-Crafts acylation
2010
NEET
MCQ
AIPMT 2010 Prelims
Among the given compounds, the most susceptible to nucleophilic attack at the carbonyl group is
A.
CH3COOCH3
B.
CH3CONH2
C.
CH3COOCOCH3
D.
CH3COCl
2009
NEET
MCQ
AIPMT 2009
Trichloroacetaldehyde, CCl3CHO reacts with chlorobenzene in presence of sulphuric acid and produces
A.


B.


C.


D.


2009
NEET
MCQ
AIPMT 2009
Propionic acid with Br2/P yields a dibromo product. Its structure would be
A.


B.
CH2(Br) $-$ CH2 $-$ COBr
C.


D.
CH2(Br) $-$ CH(Br) $-$ COOH
2008
NEET
MCQ
AIPMT 2008
A strong base can abstract an $\alpha $-hydrogen from
A.
ketone
B.
alkane
C.
alkene
D.
amine
2008
NEET
MCQ
AIPMT 2008
The relative reactivities of acyl compounds towards nucleophilic substitution are in the order of
A.
Acid anhydride > Amide > Ester > Acyl chloride
B.
Acyl chloride > Ester > Acid anhydride > Amide
C.
Acyl chloride > Acid anhydride > Ester > Amide
D.
Ester > Acyl chloride > Amide > Acid anhydride.
2008
NEET
MCQ
AIPMT 2008
Acetophenone when reacted with a base, C2H5ONa, yields a stable compound which has the structure
A.
B.
C.
D.
2007
NEET
MCQ
AIPMT 2007
Which of the following represents the correct order of the acidity in the given compounds ?
A.
FCH2COOH > CH3COOH > BrCH2COOH > ClCH2COOH
B.
BrCH2COOH > ClCH2COOH > FCH2COOH > CH3COOH
C.
FCH2COOH > ClCH2COOH > BrCH2COOH > CH3COOH
D.
CH3COOH > BrCH2COOH > ClCH2COOH > FCH2COOH
2007
NEET
MCQ
AIPMT 2007
Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is called
A.
Cope reduction
B.
Dow reduction
C.
Wolf-Kishner reduction
D.
Clemmensen reduction
2007
NEET
MCQ
AIPMT 2007
Which one of the following on treatment with 50% aqueous sodium hydroxide yields the corresponding alcohol and acid?
A.
C6H5CHO
B.
CH3CH2CH2CHO
C.
D.
C6H5CH2CHO
2007
NEET
MCQ
AIPMT 2007
Consider the following compounds
The correct decreasing order of their reactivity towards hydrolysis is
The correct decreasing order of their reactivity towards hydrolysis is
A.
(i) > (ii) > (iii) > (iv)
B.
(iv) > (ii) > (i) > (iii)
C.
(ii) > (iv) > (i) > (iii)
D.
(ii) > (iv) > (iii) > (i)
2007
NEET
MCQ
AIPMT 2007
The product formed in Aldol condensation is
A.
a beta-hydroxy aldehyde or a beta-hydroxy ketone
B.
an alpha-hydroxy aldehyde or ketone
C.
an alpha, beta unsaturated ester
D.
a beta-hydroxy acid.
2006
NEET
MCQ
AIPMT 2006
Nucleophilic addition reaction will be most favoured in
A.
CH3CHO
B.
C.
(CH3)2C $=$ O
D.
CH3CH2CHO
2006
NEET
MCQ
AIPMT 2006
Self condensation of two moles of ethyl acetate in presence of sodium ethoxide yields
A.
ethyl propionate
B.
ethyl butyrate
C.
acetoacetic ester
D.
methyl acetoacetate
2006
NEET
MCQ
AIPMT 2006
In a set of reactions propionic acid yielded a compound D.

The structure of D would be

The structure of D would be
A.
CH3CH2NH2
B.
CH3CH2CH2NH2
C.
CH3CH2CONH2
D.
CH3CH2NHCH3
2006
NEET
MCQ
AIPMT 2006
A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of $\alpha $-hydrixy acid. The carbonyl compound is
A.
formaldehyde
B.
acetaldehyde
C.
acetone
D.
diethyl ketone
2005
NEET
MCQ
AIPMT 2005
In a set of reactions acetic acid yielded a product D.

The structure of D would be

The structure of D would be
A.
B.
C.
D.
2005
NEET
MCQ
AIPMT 2005
The major organic product formed from the following reaction :
is
is
A.
B.
C.
D.
2004
NEET
MCQ
AIPMT 2004
The $-$ OH group of an alcohol or the $-$ COOH group of a carboxylic acid can be replaced by $-$ Cl using
A.
phosphorus pentachloride
B.
hypochlorous acid
C.
chlorine
D.
hydrochloric acid
2004
NEET
MCQ
AIPMT 2004
Which one of the following can be oxidised to the corresponding carbonyl compound?
A.
2-Hydroxypropane
B.
ortho-Nitrophenol
C.
Phenol
D.
2-Methyl-2-hydroxypropane
2003
NEET
MCQ
AIPMT 2003
In a set of the given reactions, acetic acid yielded a product C.

Product $C$ would be

Product $C$ would be
A.
CH3CH(OH)C2H5
B.
CH3COC6H6
C.
CH3CH(OH)C6H5
D.
2003
NEET
MCQ
AIPMT 2003
When $m$-chlorobenzaldehyde is treated with 50% KOH solution, the product(s) obtained is (are)
A.


B.


C.


D.


2003
NEET
MCQ
AIPMT 2003
$A$ and $B$ in the following reactions are :


A.
B.
C.


D.


2003
NEET
MCQ
AIPMT 2003
In this reaction :
CH3CHO + HCN $ \to $ CH3CH(OH)CN
$\buildrel {HOH} \over \longrightarrow $ CH3CH(OH)COOH
an asymmetric centre is generated. The acid obtained would be
CH3CHO + HCN $ \to $ CH3CH(OH)CN
$\buildrel {HOH} \over \longrightarrow $ CH3CH(OH)COOH
an asymmetric centre is generated. The acid obtained would be
A.
$D$-isomer
B.
$L$-isomer
C.
50% $D$ + 50% $L$-isomer
D.
20% $D$ + 80% $L$-isomer
2002
NEET
MCQ
AIPMT 2002

In the above reaction product P is
A.
B.
C.
D.
2002
NEET
MCQ
AIPMT 2002
In the following reaction product $P$ is
A.
RCH2OH
B.
RCOOH
C.
RCHO
D.
RCH3
2002
NEET
MCQ
AIPMT 2002
are
A.
resonating structures
B.
tautomers
C.
geometrical isomers
D.
optical isomers.
2001
NEET
MCQ
AIPMT 2001
Which of the following is incorrect?
A.
FeCl3 is used in detection of phenol.
B.
Fehling solution is used in detection of glucose
C.
Tollen's reagent is used in detection of unsaturation.
D.
NaHSO3 is used in detection of carbonyl compound.
2001
NEET
MCQ
AIPMT 2001
Which of the following give positive Fehling solution test?
A.
Sucrose
B.
Glucose
C.
Fats
D.
Protein
2001
NEET
MCQ
AIPMT 2001
Which alkene on ozonolysis gives CH3CH2CHO and CH3COCH3?
A.
B.
CH3CH2CH $=$ CHCH2CH3
C.
CH3CH2CH $=$ CHCH3
D.
2000
NEET
MCQ
AIPMT 2000
Polarisation in acrolein can be described as
A.
B.
C.
D.
2000
NEET
MCQ
AIPMT 2000
First product of the reaction between RCHO and NH2NH2 is
A.
RCH $=$ NNH2
B.
RCH $=$ NH
C.
RCH2NH2
D.
RCON3
2000
NEET
MCQ
AIPMT 2000
Reduction by LiAlH4 of hydrolysed product of an ester gives
A.
two alcohols
B.
two aldehydes
C.
one acid and one alcohol
D.
two acids.











