For the given reaction
The total number of possible products formed by tertiary carbocation of A is ____________.
Explanation:
Total 4 products are possible through 3° carbocation
The number of possible isomeric products formed when 3-chloro-1-butene reacts with $\mathrm{HCl}$ through carbocation formation is __________.
Explanation:
Total Possible Isomeric product = 1+3 = 4
Molar mass of the hydrocarbon (X) which on ozonolysis consumes one mole of $\mathrm{O}_{3}$ per mole of $(\mathrm{X})$ and gives one mole each of ethanal and propanone is _________ $\mathrm{g}~ \mathrm{mol}^{-1}$
(Molar mass of $\mathrm{C}: 12 \mathrm{~g} \mathrm{~mol}^{-1}, \mathrm{H}: 1 \mathrm{~g} \mathrm{~mol}^{-1}$ )
Explanation:
Hydrocarbon $(\mathrm{X})$ is 2-methyl-but-2-ene $\left(\mathrm{C}_5 \mathrm{H}_{10}\right)$
And the molecular mass is $5(12)+10(1)=70$.
Number of bromo derivatives obtained on treating ethane with excess of $\mathrm{Br}_{2}$ in diffused sunlight is ___________
Explanation:
17 mg of a hydrocarbon (M.F. $\mathrm{C_{10}H_{16}}$) takes up 8.40 mL of the H$_2$ gas measured at 0$^\circ$C and 760 mm of Hg. Ozonolysis of the same hydrocarbon yields
The number of double bond/s present in the hydrocarbon is ___________.
Explanation:
Mole of $\mathrm{H}_{2}$ gas
$\Rightarrow 1 \times \frac{8.40}{1000}=\mathrm{n} \times 0.0821 \times 273$
$\Rightarrow \mathrm{n}=3.75 \times 10^{-4}$
Hydrogen molecule used for 1 molecule of hydrocarbon is 3
$=\frac{3.75 \times 10^{-4}}{1.25 \times 10^{-4}}=3$
Maximum number of isomeric monochloro derivatives which can be obtained from 2,2,5,5-tetramethylhexane by chlorination is _____________
Explanation:
Total numbers of isomer = 03
The major product 'A' of the following given reaction has _____________ sp2 hybridized carbon atoms.
Explanation:
Number of sp2 hybridised carbon atoms = 2
Consider the above chemical reaction. The total number of stereoisomers possible for Product 'P' is _____________.
Explanation:
The total number of products possible = 2
is _______________.
Explanation:
Numbers of $\sigma$ bonds = 10
The number of sp2 hybridized carbon atom(s) present in the product is ________.
Explanation:
All the 7-carbon-atoms in product are sp2 hybridised.
Explanation:
C4H10(g) + ${{13} \over 2}$O2(g) $ \to $ 4CO2(g) + 5H2O(l)
$ \therefore $ No. of moles of O2 required to oxidise 1 mole of propane = 5
$ \therefore $ No. of moles of O2 required to oxidise 1 mole of butane = ${{13} \over 2}$
So, No. of moles of O2 required to oxidise 1 mole of
propane and 2 moles of butane = 5 + 2 $ \times $ ${{13} \over 2}$ = 18
Explanation:
(A is a lowest molecular weight alkyne)
Explanation:
Consider the depicted hydrogen (H) in the hydrocarbons given below. The most acidic hydrogen (H) is
B forms most stable conjugate base and hence $B$ is most acidic$
\text { Answer: Option (B) }
$
The correct statement with respect to product Y is
The major product of the following reaction is
In the following reaction,
The structure of the major 'X' is
The reagent(s) for the following conversion,
$ \begin{aligned} &\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}_2+\mathrm{NOCl} \rightarrow \mathrm{P}\\ &\text { Identify the adduct. } \end{aligned} $
Step 3:
The IUPAC name of $\mathrm{C}_6 \mathrm{H}_5 \mathrm{COCl}$ is
Benzoyl chloride
Benzene chloroketone
Benzene carbonyl chloride
Chlorophenyl ketone
The IUPAC name of the compound is benzene carbonyl chloride.In the following reaction sequence, the major product $\mathbf{P}$ is formed.
Glycerol reacts completely with excess $\mathbf{P}$ in the presence of an acid catalyst to form $\mathbf{Q}$. Reaction of $\mathbf{Q}$ with excess $\mathrm{NaOH}$ followed by the treatment with $\mathrm{CaCl}_2$ yields Ca-soap $\mathbf{R}$, quantitatively. Starting with one mole of $\mathbf{Q}$, the amount of $\mathbf{R}$ produced in gram is __________.
[Given, atomic weight: $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Na}=23, \mathrm{Cl}=35, \mathrm{Ca}=40$ ]
Explanation:
$\therefore 1$ mole $Q$ produce $\frac{3}{2}$ moles $R$
$\therefore$ Mass of $R$ produce $=\frac{3}{2} \times 606=909 \mathrm{~g}$
Explanation:
Explanation:
Explanation:
If the reaction sequence given below is carried out with 15 moles of acetylene, the amount of the product $\mathbf{D}$ formed (in $\mathrm{g}$ ) is ___________ .
The yields of $\mathbf{A}, \mathbf{B}, \mathbf{C}$ and $\mathbf{D}$ are given in parentheses.
[Given: Atomic mass of $\mathrm{H}=1, \mathrm{C}=12, \mathrm{O}=16, \mathrm{Cl}=35$ ]
Explanation:
Molecular formula of D is C8H8O2
Molar mass of D is ($12\times8+8\times1+16\times2$) = 136 g
$\therefore$ Mass of D is 136
x g and y g are mass of R and U, respectively.
(Use : Molar mass (in g mol$-$1) of H, C and O as 1, 12 and 16, respectively)
The value of x is ________.
Explanation:
$M{g_2}{C_3} + 4{H_2}O \to 2Mg{(OH)_2} + C{H_3} - \mathop {\mathop C\limits_{(P)} }\limits_{{\mathop{\rm Propyne}\nolimits} } \equiv CH$
Sodium amide (NaNH2) takes proton from alkyne to form acetylide ion which, attacks on Me$-$I to give an alkyne with one more carbon.
Mass of P formed = 4.0 g
Molar mass of P formed = 40 g mol$-$1
Number of moles of P = ${{Mass\,of\,P(W)} \over {Molar\,mass\,of\,P(M)}} = {4 \over {40}} = 0.1$ mol
1 mole of P forms 75% i.e., 0.75 = 0.075 mole of Q
Polymerisation of alkyne (Butyne) occurs in presence of red hot iron tube to form benzene derivative.
3 moles of alkyne forms 40% i.e., 0.40 mole of benzene derivative, R.
0.075 mole of Q forms ${{0.40} \over 3} \times 0.075 = 0.01$ mole of R.
Molar mass of R = 162 g/mol
Mass of R formed or value of x = Molar mass $\times$ Number of moles = 162 $\times$ 0.01 = 1.62 g
Explanation:
$ 60+32+8=100 $
The value of $\mathrm{Y}=0.032 \times 100=3.2$
Explanation:
Compound (P) has total number of hydroxyl groups = 6
The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is _______.
Explanation:
(2) Since, bromide (Br–) is a good leaving group, elimination using strong base takes place using strong base (KOH) take via E2 mechanism. This is also called $\beta $ elimination.
(3) There are 3 different types of protons :
(iv) The strong base abstracts $\beta $ hydrogen (H1 or H2 or H3) with simultaneous loss of bromide ion forming an alkene. This alkene can exist in 2 conformations, E and Z.
(a) Elimination of H1 proton :
This product can exist in 2 conformations, E and Z.
(b) Elimination of H2 proton :
Since, the groups about sp2 hybridised carbon of cyclopentane is fixed no E and Z forms are possible. This molecule has only one conformation.
(c) Elimination of H3 proton :
This product can exist in 2 conformations, E and Z.
Hence, a total of 5 products are possible.
The maximum number of isomers (including stereoisomers) that are possible on mono-chlorination of the following compound, is ____________.
Explanation:
(i) The monochlorination products obtained depends upon the kinds of hydrogen present in the molecule.
(ii) There are four different types of hydrogen in the molecule; $\mathrm{H}_a, \mathrm{H}_b, \mathrm{H}_c$ and $\mathrm{H}_d$.
(iii) The monochlorination products obtained on replacement of these hydrogen are as follows :
(a) Replacing $\mathrm{H}_a$ with chlorine :
Since, the carbon is a chiral; only one monochlorination isomer is possible when $\mathrm{H}_a$ is replaced by chlorine.
(b) Replacing $\mathrm{H}_b$ with chlorine :
Since all the carbons are a chiral; only one monochlorination product is possible by when $\mathrm{H}_b$ replaced by Cl .
(c) Replacing $\mathrm{H}_c$ with chlorine
The carbon on which hydrogen is replaced by chlorine becomes chiral; hence R/S isomers exist.
Also, carbon adjacent to the carbon on which hydrogen $\left(\mathrm{H}_c\right)$ is replaced, is also chiral; hence, it will also exist as a pair of enantiomer $R / S$ four monochlorination products (which are stereoisomers or optical isomers) are possible.
(d) Replacing $\mathrm{H}^d$ by chlorine :
The central carbon $\left({ }^*\right)$ becomes chiral when $\mathrm{H}^d$ is replaced by chlorine; hence $R / S$ isomers exist. Two monochlorination products are possible (stereoisomers or optical isomers) are possible.
Total number of isomers possible are 8.
Choose the correct option(s).
Among the following reaction(s), which gives(give) tert-butyl benzene as the major product is(are)
In the following reactions, the product S is
The major product U in the following reactions is
In the following reaction, the major product is
Among P, Q, R and S, the aromatic compound(s) is(are)
$ \text { The major products } \mathbf{P} \text { and } \mathbf{Q} \text { are } $
$ \text { It is a two step reaction: } $
Hence, product $P$ is cumene.
The cumene hydroperoxide on acidic hydrolysis produces phenol and acetone.
Explanation:
Now, assume moles of ${C_2}{H_6} = x$
$\therefore$ Moles of ${C_2}{H_5}Br = x$ when 100% yield.
Given that 90% yield of ${C_2}{H_5}Br$ happens.
$\therefore$ Moles of ${C_2}{H_5}Br = x \times {{90} \over {100}} = 0.9x$
Now, from 2 moles of ${C_2}{H_5}Br$ 1 mole of ${C_4}{H_{10}}$ produced.
$\therefore$ From 0.9x moles of ${C_2}{H_5}Br$ ${1 \over 2} \times 0.9x$ moles of ${C_4}{H_{10}}$ produced when 100% yield happens. But given that 85% yield of ${C_4}{H_{10}}$ happens.
$\therefore$ Moles of ${C_4}{H_{10}} = {1 \over 2} \times 0.9x \times {{85} \over {100}}$
$ = {{(0.9 \times 0.85)x} \over 2}$
According to question,
${{(0.9 \times 0.85)x} \over 2} = {{55} \over {58}}$
$ \Rightarrow x = {{55} \over {29 \times 0.9 \times 0.85}} = 2.48$
$\therefore$ Volume of ${C_2}{H_6} = 2.48 \times 22.4$ Litres
$ = 55.552$ Litres