Chemical Kinetics and Nuclear Chemistry

2020 Q151 JEE Mains Numerical
14 Mar 2026
During the nuclear explosion, one of the products is 90Sr with half life of 6.93 years. If 1 $\mu $ g of 90Sr was absorbed in the bones of newly born baby in placed of Ca, how much time, in years, is required to reduce much time, in year, is required to reduce it by 90% if it not lost metabolically.
2020 Q152 JEE Mains MCQ
14 Mar 2026
Consider the following reactions

A $ \to $ P1 ; B $ \to $ P2 ; C $ \to $ P3 ; D $ \to $ P4,

The order of the above reactions are a, b, c, and d, respectively. The following graph is obtained when log[rate] vs. log[conc.] are plotted JEE Main 2020 (Online) 6th September Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 148 English
Among the following, the correct sequence for the order of the reactions is :
A.
d > b > a > c
B.
d > a > b > c
C.
a > b > c > d
D.
c > a > b > d
2020 Q153 JEE Mains MCQ
14 Mar 2026
The rate constant (k) of a reaction is measured at differenct temperatures (T), and the data are plotted in the given figure. The activation energy of the reaction in kJ mol–1 is :
(R is gas constant) JEE Main 2020 (Online) 5th September Evening Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 149 English
A.
R
B.
2R
C.
${1 \over R}$
D.
${1 \over {2R}}$
2020 Q154 JEE Mains MCQ
14 Mar 2026
A flask contains a mixture of compounds A and B. Both compounds decompose by first-order kinetics. The half-lives for A and B are 300 s and 180 s, respectively. If the concentrations of A and B are equal initially, the time required for the concentration of A to be four times that of B(in s) :
(Use ln 2 = 0.693)
A.
180
B.
120
C.
300
D.
900
2020 Q155 JEE Mains MCQ
14 Mar 2026
For the reaction
2A + 3B + ${3 \over 2}$C $ \to $ 3P, which statement is correct ?
A.
${{d{n_A}} \over {dt}} = {{d{n_B}} \over {dt}} = {{d{n_C}} \over {dt}}$
B.
${{d{n_A}} \over {dt}} = {2 \over 3}{{d{n_B}} \over {dt}} = {3 \over 4}{{d{n_C}} \over {dt}}$
C.
${{d{n_A}} \over {dt}} = {3 \over 2}{{d{n_B}} \over {dt}} = {3 \over 4}{{d{n_C}} \over {dt}}$
D.
${{d{n_A}} \over {dt}} = {2 \over 3}{{d{n_B}} \over {dt}} = {4 \over 3}{{d{n_C}} \over {dt}}$
2020 Q156 JEE Mains MCQ
14 Mar 2026
It is true that :
A.
A first order reaction is always a single step reaction
B.
A zero order reaction is a multistep reaction
C.
A zero order reaction is a single step reaction
D.
A second order reaction is always a multistep reaction
2020 Q157 JEE Mains MCQ
14 Mar 2026
The results given in the below table were obtained during kinetic studies of the following reaction

2A + B $ \to $ C + D JEE Main 2020 (Online) 2nd September Evening Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 155 English
X and Y in the given table are respectively :
A.
0.3, 0.4
B.
0.4, 0.3
C.
0.4, 0.4
D.
0.3, 0.3
2020 Q158 JEE Mains MCQ
14 Mar 2026
For the following reactions
$A\buildrel {700K} \over \longrightarrow {\mathop{\rm Product}\nolimits} $
$A\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{catalyst}^{500K}} {\mathop{\rm Product}\nolimits} $
it was found that Ea is decreased by 30 kJ/mol in the presence of catalyst.
If the rate remains unchanged, the activation energy for catalysed reaction is (Assume pre exponential factor is same):
A.
198 kJ/mol
B.
135 kJ/mol
C.
105 kJ/mol
D.
75 kJ/mol
2020 Q159 JEE Mains MCQ
14 Mar 2026
Consider the following plots of rate constant versus ${1 \over T}$ for four different reactions. Which of the following orders is correct for the activation energies of these reactions?

JEE Main 2020 (Online) 8th January Evening Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 158 English
A.
Ec > Ea > Ed > Eb
B.
Ea > Ec > Ed > Eb
C.
Eb > Ea > Ed > Ec
D.
Eb > Ed > Ec > Ea
2020 Q160 JEE Mains MCQ
14 Mar 2026
The rate of a certain biochemical reaction at physiological temperature (T) occurs 106 times faster with enzyme than without. The change in the activation energy upon adding enzyme is :
A.
+ 6RT
B.
– 6 (2.303)RT
C.
– 6RT
D.
+ 6(2.303)RT
2020 Q161 JEE Mains MCQ
14 Mar 2026
For the reaction
2H2(g) + 2NO(g) $ \to $ N2(g) + 2H2O(g)
the observed rate expression is, rate = Kf[NO]2[H2]. The rate expression for the reverse reaction is :
A.
Kb[N2][H2O]
B.
Kb[N2][H2O]2/[H2]
C.
Kb[N2][H2O]2/[NO]
D.
Kb[N2][H2O]2
2019 Q162 JEE Mains MCQ
14 Mar 2026
NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as per the equation,
2N2O5(g) $ \to $ 4NO2(g) + O2(g).
The initial concentration of N2O5 is 3.00 mol L–1 and it is 2.75 mol L–1 after 30 minutes. The rate of formation of NO2 is :
A.
2.083 × 10–3 mol L–1 min–1
B.
8.333 × 10–3 mol L–1 min–1
C.
4.167 × 10–3 mol L–1 min–1
D.
1.667 × 10–2 mol L–1 min–1
2019 Q163 JEE Mains MCQ
14 Mar 2026
In the following reaction; xA $ \to $ yB
${\log _{10}}\left[ { - {{d\left[ A \right]} \over {dt}}} \right] = {\log _{10}}\left[ {{{d\left[ B \right]} \over {dt}}} \right] + 0.3010$
'A' and 'B' respectively can be :
A.
n-Butane and Iso-butane
B.
C2H4 and C4H8
C.
C2H4 and C6H6
D.
N2O4 and NO2
2019 Q164 JEE Mains MCQ
14 Mar 2026
For the reaction of H2 with I2, the rate constant is 2.5 × 10–4 dm3 mol–1s–1 at 327°C and 1.0 dm3 mol–1 at 527°C. The activation energy for the reaction, in kJ mole–1 is : (R = 8.314 JK–1 mol–1 )
A.
59
B.
166
C.
72
D.
150
2019 Q165 JEE Mains MCQ
14 Mar 2026
A bacterial infection in an internal wound grows as N'(t) = N0 exp(t), where the time t is in hours. A does of antibiotic, taken orally, needs 1 hour to reach the wound. Once it reaches there, the bacterial population goes down as ${{dN} \over {dt}} = - 5{N^2}$. What will be the plot of ${{{N_0}} \over N}$ vs. t after 1 hour?
A.
JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 165 English Option 1
B.
JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 165 English Option 2
C.
JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 165 English Option 3
D.
JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 165 English Option 4
2019 Q166 JEE Mains MCQ
14 Mar 2026
Consider the given plot of enthalpy of the following reaction between A and B.
A+ B $ \to $ C + D
Identify the incorrect statement. JEE Main 2019 (Online) 9th April Evening Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 166 English
A.
Formation of A and B from C has highest enthalpy of activation.
B.
D is kinetically stable product.
C.
C is the thermodynamically stable product
D.
Activation enthalpy to form C is 5kJ mol–1 less than that to form D.
2019 Q167 JEE Mains MCQ
14 Mar 2026
The given plots represent the variation of the concentration of a reactant R with time for two different reactions (i) and (ii). The respective orders of the reactions are : JEE Main 2019 (Online) 9th April Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 167 English
A.
0,1
B.
1,0
C.
0,2
D.
1,1
2019 Q168 JEE Mains MCQ
14 Mar 2026
For a reaction scheme $A\buildrel {{k_1}} \over \longrightarrow B\buildrel {{k_2}} \over \longrightarrow C$,

if the rate of formation of B is set to be zero then the concentration of B is given by :
A.
${k_1}{k_2}[A]$
B.
$\left( {{{{k_1}} \over {{k_2}}}} \right)[A]$
C.
$({k_1} + {k_2})[A]$
D.
$({k_1} - {k_2})[A]$
2019 Q169 JEE Mains MCQ
14 Mar 2026
For the reaction 2A + B $ \to $ C, the values of initial rate at diffrent reactant concentrations are given in the table below. The rate law for the reaction is :

[A] (mol L-1) [B] (mol L-1) Initial Rate (mol L-1s-1)
0.05 0.05 0.045
0.10 0.05 0.090
0.20 0.10 0.72
A.
Rate = k[A][B]2
B.
Rate = k[A]2[B]2
C.
Rate = k[A]2[B]
D.
Rate = k[A][B]
2019 Q170 JEE Mains MCQ
14 Mar 2026
For a reaction consider the plot of $\ell $n k versus 1/T given in the figure. If the rate constant of this reaction at 400 K is 10–5 s–1, then the rate constant at 500 K is –

JEE Main 2019 (Online) 12th January Evening Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 170 English
A.
10$-$4 s$-$1
B.
4 $ \times $ 10$-$4 s$-$1
C.
10$-$6 s$-$1
D.
2 $ \times $ 10$-$4 s$-$1
2019 Q171 JEE Mains MCQ
14 Mar 2026
Decomposition of X exhibits a rate constant of 0.05 $\mu $g/year. How many year are required for the decomposition of 5$\mu $g of X into 2.5 $\mu $g?
A.
50
B.
20
C.
25
D.
40
2019 Q172 JEE Mains MCQ
14 Mar 2026
The reaction 2X $ \to $ B is a zeroth order reaction. If the initial concentration of X is 0.2 M, the half-life is 6 h. When the initial concentration of X is 0.5 M, the time required to reach its final concentration of 0.2 M will be:
A.
18.0 h
B.
9.0 h
C.
7.2 h
D.
12.0 h
2019 Q173 JEE Mains MCQ
14 Mar 2026
If a reaction follows the Arrhenius equation, the plot ln k vs ${1 \over {\left( {RT} \right)}}$ gives straight line with a gradient ($-$ y) unit.

The energy required to active the reactant is :
A.
y unit
B.
y/R unit
C.
yR unit
D.
$-$y unit
2019 Q174 JEE Mains MCQ
14 Mar 2026
For an elementary chemical reaction,

JEE Main 2019 (Online) 10th January Evening Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 174 English

the expression for ${{d\left[ A \right]} \over {dt}}$ is
A.
2K1[A2] – K –1 [A]2
B.
K1[A2] – K –1 [A]2
C.
K1[A2] + K –1 [A]2
D.
2K1[A2] – 2K –1 [A]2
2019 Q175 JEE Mains MCQ
14 Mar 2026
Consider the given plots for a reaction obeying Arrhenius equation (0oC < T < 300oC) : (K and Ea are rate constant and activation energy, respectively)

JEE Main 2019 (Online) 10th January Morning Slot Chemistry - Chemical Kinetics and Nuclear Chemistry Question 175 English

Choose the correct option :
A.
I is right but II is wrong
B.
Both I and II are correct
C.
Both I and II are wrong
D.
I is wrong but II is right
2019 Q176 JEE Mains MCQ
14 Mar 2026
For the reaction, 2A + B $ \to $ products, when the concentrations of A and B both were doubled, the rate of the reaction increased from 0.3 mol L$-$1s$-$1 to 2.4 mol L$-$1s$-$1. When the concentration of A alone is doubled, the rate increased from 0.3 mol L$-$1s$-$1 to 0.6 mol L$-$1s$-$1.
A.
Total order of the reaction is 4
B.
Order of the reaction with respect to B is 2
C.
Order of the reaction with respect to B is 1
D.
Order of the reaction with respect to A is 2
2019 Q177 JEE Mains MCQ
14 Mar 2026
The following results were obtained during kinetic studies of the reaction ;

2A + B $ \to $ Products

Experiment [A] (in mol L$-$1) [b] (in mol L$-$1) Initial Rate of reaction
(In mol L$-$1 min$-$1)
I 0.10 0.20 6.93 G 10$-$3
II 0.10 0.25 6.93 G 10$-$3
III 0.20 0.30 1.386 G 10$-$2


The time (in minutes) required to consume half of A is :
A.
5
B.
10
C.
1
D.
100
2018 Q178 JEE Mains MCQ
14 Mar 2026
If 50% of a reaction occurs in 100 second and 75% of the reaction occurs in 200 secod, the order of this reaction is :
A.
Zero
B.
1
C.
2
D.
3
2018 Q179 JEE Mains MCQ
14 Mar 2026
At 518oC the rate of decomposition of a sample of gaseous acetaldehyde initially at a pressure of 363 Torr, was 1.00 Torr s–1 when 5% had reacted and 0.5 Torr s–1 when 33% had reacted. The order of the reaction is
A.
0
B.
2
C.
3
D.
1
2018 Q180 JEE Mains MCQ
14 Mar 2026
For a first order reaction, A $ \to $ P, t1/2 (half-life) is 10 days The time required for ${1 \over 4}$th conversion of A (in days) is : (ln 2 = 0.693,    ln 3 = 1.1)
A.
5
B.
3.2
C.
4.1
D.
2.5
2018 Q181 JEE Mains MCQ
14 Mar 2026
N2O5 decomposes to NO2 and O2 and follows first order kinetics. After 50 minutes, the pressure inside the vessel increases from 50 mmHg to 87.5 mmHg. The pressure of the gaseous mixture after 100 minute at constant temperature will be :
A.
175.0 mmHg
B.
116.25 mmHg
C.
136.25 mmHg
D.
106.25 mmHg
2017 Q182 JEE Mains MCQ
14 Mar 2026
The rate of a reaction quadruples when the temperature changes from 300 to 310 K. The activation energy of this reaction is :

(Assume activation energy and preexponential factor are independent of temperature; ln 2 = 0.693; R = 8.314 J mol−1 K−1)
A.
107.2 kJ mol$-$1
B.
53.6 kJ mol$-$1
C.
26.8 kJ mol$-$1
D.
214.4 kJ mol$-$1
2017 Q183 JEE Mains MCQ
14 Mar 2026
The rate of a reaction A doubles on increasing the temperature from 300 to 310 K. By how much, the temperature of reaction B should be Increased from 300 K so that rate doubles if activation energy of the reaction B is twice to that of reaction A.
A.
9.84 K
B.
4.92 K
C.
2.45 K
D.
19.67 K
2017 Q184 JEE Mains MCQ
14 Mar 2026
Two reactions R1 and R2 have identical pre-exponential factors. Activation energy of R1 exceeds that of R2 by 10 kJ mol–1. If k1 and k2 are rate constants for reactions R1 and R2 respectively at 300 K, then ln(k2/k1) is equal to :
(R = 8.314 J mol–1 K–1)
A.
12
B.
6
C.
4
D.
8
2016 Q185 JEE Mains MCQ
14 Mar 2026
The rate law for the reaction below is given by the expression k [A] [B]

A + B $ \to $ Product

If the concentration of B is increased from 0.1 to 0.3 mole, keeping the value of A at 0.1 mole, the rate constant will be :
A.
k
B.
k/3
C.
3k
D.
9k
2016 Q186 JEE Mains MCQ
14 Mar 2026
The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two step process shown below :

O3(g) + Cl${^ \bullet }$ (g) $ \to $ O2(g) + ClO${^ \bullet }$ (g) . . . . . .(i)

ki = 5.2 × 109 L mol−1 s−1

ClO${^ \bullet }$(g) + O${^ \bullet }$(g) $ \to $ O2(g) + Cl${^ \bullet }$ (g) . . . . . . (ii)

kii = 2.6 × 1010 L mol−1 s−1

The closest rate constant for the overall reaction O3(g) + O${^ \bullet }$ (g) $ \to $ 2 O2(g) is :
A.
5.2 × 109 L mol−1 s−1
B.
2.6 × 1010 L mol−1 s−1
C.
3.1 × 1010 L mol−1 s−1
D.
1.4 × 1020 L mol−1 s−1
2016 Q187 JEE Mains MCQ
14 Mar 2026
Decomposition of H2O2 follows a first order reaction. In fifty minutes the concentration of H2O2 decreases from 0.5 to 0.125 M in one such decomposition. When the concentration of H2O2 reaches 0.05 M, the rate of formation of O2 will be :
A.
6.93 $\times$ 10-4 mol min-1
B.
6.96 $\times$ 10-2 mol min-1
C.
1.34 $\times$ 10-2 mol min-1
D.
2.66 L min–1 at STP
2015 Q188 JEE Mains MCQ
14 Mar 2026
Higher order (>3) reactions are rare due to
A.
increase in entropy and activation energy as more molecules are involved
B.
shifting of equilibrium towards reactants due to elastic collisions
C.
loss of active species on collision
D.
low probability of simultaneous collision of all the reacting species
2014 Q189 JEE Mains MCQ
14 Mar 2026
For the non – stoichiometre reaction 2A + B $\to$ C + D, the following kinetic data were obtained in three separate experiments, all at 298 K.
Initial Concentration (A) Initial Concentration (B) Initial rate of formation of C (mol L-1 s-1)
0.1 M 0.1 M 1.2 x 10-3
0.1 M 0.2 M 1.2 x 10-3
0.2 M 0.1 M 2.4 x 10-3
The rate law for the formation of C is:
A.
${{dc} \over {dt}} = k[A]{[B]^2}$
B.
${{dc} \over {dt}} = k[A]$
C.
${{dc} \over {dt}} = k[A]{[B]}$
D.
${{dc} \over {dt}} = k[A^2]{[B]}$
2013 Q190 JEE Mains MCQ
14 Mar 2026
The rate of a reaction doubles when its temperature changes from 300K to 310K. Activation energy of such a reaction will be:(R = 8.314 JK–1 mol–1 and log 2 = 0.301)
A.
48.6 kJ mol–1
B.
58.5 kJ mol–1
C.
60.5 kJ mol–1
D.
53.6 kJ mol–1
2012 Q191 JEE Mains MCQ
14 Mar 2026
For a first order reaction, (A) $\to$ products, the concentration of A changes from 0.1 M to 0.025 M in 40 minutes. The rate of reaction when the concentration of A is 0.01 M is :
A.
1.73 x 10–5 M/ min
B.
3.47 x 10–4 M/min
C.
3.47 x 10–5 M/min
D.
1.73 x 10–4 M/min
2011 Q192 JEE Mains MCQ
14 Mar 2026
The rate of a chemical reaction doubles for every 10oC rise of temperature. If the temperature is raised by 50oC , the rate of the reaction increases by about :
A.
24 times
B.
32 times
C.
64 times
D.
10 times
2010 Q193 JEE Mains MCQ
14 Mar 2026
The time for half life period of a certain reaction A $\to$ products is 1 hour. When the initial concentration of the reactant ‘A’, is 2.0 mol L–1, how much time does it take for its concentration to come from 0.50 to 0.25 mol L–1 if it is a zero order reaction ?
A.
4 h
B.
0.5 h
C.
0.25 h
D.
1 h
2010 Q194 JEE Mains MCQ
14 Mar 2026

Consider the reaction :

Cl2(aq) + H2S(aq) → S(s) + 2H+ (aq) + 2Cl (aq)

The rate equation for this reaction is rate = k [Cl2] [H2S]

Which of these mechanisms is/are consistent with this rate equation?

(A) Cl2 + H2S $\to$ H+ + Cl + Cl+ + HS (slow)

Cl+ + HS $\to$ H+ + Cl + S (fast)

(B) H2S $ \Leftrightarrow $ H+ + HS (fast equilibrium)

Cl2 + HS $\to$ 2Cl + H+ + S (slow)

A.
B only
B.
Both A and B
C.
Neither A nor B
D.
A only
2009 Q195 JEE Mains MCQ
14 Mar 2026
The half life period of a first order chemical reaction is 6.93 minutes. The time required for the completion of 99% of the chemical reaction will be (log 2=0.301) :
A.
230.3 minutes
B.
23.03 minutes
C.
46.06 minutes
D.
460.6 minutes
2008 Q196 JEE Mains MCQ
14 Mar 2026
For a reaction ${1 \over 2}A \to 2B$ rate of disappearance of ‘A’ is related to the rate of appearance of ‘B’ by the expression
A.
$ - {{d[A]} \over {dt}}$ = ${1 \over 2}{{d[B]} \over {dt}}$
B.
$ - {{d[A]} \over {dt}}$ = ${1 \over 4}{{d[B]} \over {dt}}$
C.
$ - {{d[A]} \over {dt}}$ = ${{d[B]} \over {dt}}$
D.
$ - {{d[A]} \over {dt}}$ = $4{{d[B]} \over {dt}}$
2007 Q197 JEE Mains MCQ
14 Mar 2026
Consider the reaction, 2A + B $\to$ products. When concentration of B alone was doubled, the half-life did not change. When the concentration of A alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is
A.
L mol-1 s-1
B.
no unit
C.
mol L-1 s-1
D.
s-1
2007 Q198 JEE Mains MCQ
14 Mar 2026
A radioactive element gets spilled over the floor of a room. Its half-life period is 30 days. If the initial activity is ten times the permissible value, after how many days will it be safe to enter the room?
A.
1000 days
B.
300 days
C.
10 days
D.
100 days
2007 Q199 JEE Mains MCQ
14 Mar 2026
Which of the following nuclear reactions will generate an isotope?
A.
neutron particle emission
B.
positron emission
C.
$\alpha$-particle emission
D.
$\beta$-particle emission
2007 Q200 JEE Mains MCQ
14 Mar 2026
The energies of activation for forward and reverse reactions for A2 + B2 $\leftrightharpoons$ 2AB are 180 kJ mol−1 and 200 kJ mol−1 respectively. The presence of catalyst lowers the activation energy of both (forward and reverse) reactions by 100 kJ mol−1. The enthalpy change of the reaction ( A2 + B2 $\to$ 2AB) in the presence of catalyst will be (in kJ mol−1)
A.
300
B.
120
C.
200
D.
20