Aldehydes, Ketones and Carboxylic Acids

15 Questions MSQ (Multiple Correct)
2025 JEE Mains MSQ
JEE Main 2025 (Online) 28th January Morning Shift

A molecule ("P") on treatment with acid undergoes rearrangement and gives ("Q"). ("Q") on ozonolysis followed by reflux under alkaline condition gives (" $R$ "). The structure of (" $R$ ") is given below.

JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 36 English

The structure of ("P") is

A.
JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 36 English Option 1
B.
JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 36 English Option 2
C.
JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 36 English Option 3
D.
JEE Main 2025 (Online) 28th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 36 English Option 4
2020 JEE Mains MSQ
JEE Main 2020 (Online) 3rd September Morning Slot
An organic compound [A], molecular formula C10H20O2 was hydrolyzed with dilute sulphuric acid to give a carboxylic acid [B] and an alcohol [C]. Oxidation of [C] with
CrO3 - H2SO4 produced [B]. Which of the following strucutres are not possible for [A]?
A.
(CH3)3 – C – COOCH2C(CH3)3
B.
CH3CH2CH2COOCH2CH2CH2CH3
C.
JEE Main 2020 (Online) 3rd September Morning Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 195 English Option 3
D.
JEE Main 2020 (Online) 3rd September Morning Slot Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 195 English Option 4
2011 JEE Mains MSQ
AIEEE 2011
Silver Mirror test is given by which one of the following compounds ?
A.
Acetone
B.
Formaldehyde
C.
Benzophenone
D.
Acetaldehyde
2023 JEE Advanced MSQ
JEE Advanced 2023 Paper 2 Online
In the following reactions, $\mathbf{P}, \mathbf{Q}, \mathbf{R}$, and $\mathbf{S}$ are the major products.

JEE Advanced 2023 Paper 2 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 14 English 1
JEE Advanced 2023 Paper 2 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 14 English 2
The correct statement(s) about $\mathbf{P}, \mathbf{Q}, \mathbf{R}$, and $\mathbf{S}$ is(are) :
A.
$\mathbf{P}$ and $\mathbf{Q}$ are monomers of polymers dacron and glyptal, respectively.
B.
$\mathbf{P}, \mathbf{Q}$, and $\mathbf{R}$ are dicarboxylic acids.
C.
Compounds $\mathbf{Q}$ and $\mathbf{R}$ are the same.
D.
$\mathbf{R}$ does not undergo aldol condensation and $\mathbf{S}$ does not undergo Cannizzaro reaction.
2023 JEE Advanced MSQ
JEE Advanced 2023 Paper 1 Online
In the following reactions, $\mathbf{P}, \mathbf{Q}, \mathbf{R}$, and $\mathbf{S}$ are the major products.

JEE Advanced 2023 Paper 1 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 15 English 1JEE Advanced 2023 Paper 1 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 15 English 2
The correct statement(s) about $\mathbf{P}, \mathbf{Q}, \mathbf{R}$, and $\mathbf{S}$ is(are) :
A.
Both $\mathbf{P}$ and $\mathbf{Q}$ have asymmetric carbon(s).
B.
Both $\mathbf{Q}$ and $\mathbf{R}$ have asymmetric carbon(s).
C.
Both $\mathbf{P}$ and $\mathbf{R}$ have asymmetric carbon(s).
D.
$\mathbf{P}$ has asymmetric carbon(s), $\mathbf{S}$ does not have any asymmetric carbon.
2022 JEE Advanced MSQ
JEE Advanced 2022 Paper 1 Online

Considering the reaction sequence given below, the correct statement(s) is(are)

JEE Advanced 2022 Paper 1 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 29 English

A.
$\mathbf{P}$ can be reduced to a primary alcohol using $\mathrm{NaBH}_{4}$.
B.
Treating $\mathbf{P}$ with conc. $\mathrm{NH}_{4} \mathrm{OH}$ solution followed by acidification gives $\mathbf{Q}$.
C.
Treating $\mathbf{Q}$ with a solution of $\mathrm{NaNO}_{2}$ in aq. $\mathrm{HCl}$ liberates $\mathrm{N}_{2}$.
D.
$\mathbf{P}$ is more acidic than $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COOH}$.
2020 JEE Advanced MSQ
JEE Advanced 2020 Paper 1 Offline
In the reaction scheme shown below Q, R and S are the major products.

JEE Advanced 2020 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English

The correct structure of
A.
S is

JEE Advanced 2020 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English Option 1
B.
Q is

JEE Advanced 2020 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English Option 2
C.
R is

JEE Advanced 2020 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English Option 3
D.
S is

JEE Advanced 2020 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English Option 4
2019 JEE Advanced MSQ
JEE Advanced 2019 Paper 2 Offline
Choose the correct option(s) for the following reaction sequence

JEE Advanced 2019 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 63 English
Consider Q, R and S as major products.
A.
JEE Advanced 2019 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 63 English Option 1
B.
JEE Advanced 2019 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 63 English Option 2
C.
JEE Advanced 2019 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 63 English Option 3
D.
JEE Advanced 2019 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 63 English Option 4
2018 JEE Advanced MSQ
JEE Advanced 2018 Paper 1 Offline
The reaction (s) leading to the formation of $1,3,5$-trimethylbenzene is (are)
A.
JEE Advanced 2018 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 76 English Option 1
B.
JEE Advanced 2018 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 76 English Option 2
C.
JEE Advanced 2018 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 76 English Option 3
D.
JEE Advanced 2018 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 76 English Option 4
2017 JEE Advanced MSQ
JEE Advanced 2017 Paper 2 Offline
Compounds $P$ and $R$ upon ozonolysis produce $Q$ and $S,$ respectively. The molecular formula of $Q$ and $S$ is ${C_8}{H_8}O.Q$ undergoes Canninzzaro reaction but not haloform reaction, whereas $S$ undergoes haloform reaction but not Cannizzaro reaction

JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 66 English
The option(s) with suitable combination of $P$ and $R,$ respectively, is (are)
A.
JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 66 English Option 1
B.
JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 66 English Option 2
C.
JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 66 English Option 3
D.
JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 66 English Option 4
2016 JEE Advanced MSQ
JEE Advanced 2016 Paper 2 Offline

Reagent(s) which can be used to bring about the following transformation is(are)

JEE Advanced 2016 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 52 English

A.
LiAlH4 in (C2H5)2O
B.
BH3 in THF
C.
NaBH4 in C2H5OH
D.
Raney Ni/H2 in THF
2016 JEE Advanced MSQ
JEE Advanced 2016 Paper 1 Offline
Positive Tollen’s test is observed for
A.
JEE Advanced 2016 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 57 English Option 1
B.
JEE Advanced 2016 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 57 English Option 2
C.
JEE Advanced 2016 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 57 English Option 3
D.
JEE Advanced 2016 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 57 English Option 4
2016 JEE Advanced MSQ
JEE Advanced 2016 Paper 1 Offline

The correct statements about of the following reaction sequence is (are)

Cumene (C9H12) $\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{(ii)\,{H_3}{O^ + }}^{(i)\,{O_2}}} $ P $\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{}^{CHC{l_3}/NaOH}} $ Q (major) + R (minor)

Q $\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{PhC{H_2}Br}^{NaOH}} $ S

A.
R is steam volatile.
B.
Q gives dark violet coloration with 1% aqueous FeCl3 solution.
C.
S gives yellow precipitate with 2, 4-dinitrophenylhydrazine.
D.
S gives dark violet coloration with 1% aqueous FeCl3 solution.
2012 JEE Advanced MSQ
IIT-JEE 2012 Paper 2 Offline

With reference to the scheme given, which of the given statement(s) about T, U, V and W is(are) correct?

IIT-JEE 2012 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 37 English

A.
T is soluble in hot aqueous NaOH.
B.
U is optically active.
C.
Molecular formula of W is C10H18O4.
D.
V gives effervescence on treatment with aqueous NaHCO3.
2012 JEE Advanced MSQ
IIT-JEE 2012 Paper 1 Offline

Identify the binary mixtures that can be separated into individual compounds, by differential extraction, as shown in the given scheme.

IIT-JEE 2012 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 32 English

A.
C6H5OH and C6H5COOH
B.
C6H5COOH and C6H5CH2OH
C.
C6H5CH2OH and C6H5OH
D.
C6H5CH2OH and C6H5CH2COOH