Heat and Thermodynamics
In a dark room with ambient temperature $\mathrm{T}_0$, a black body is kept at a temperature T . Keeping the temperature of the black body constant (at T), sunrays are allowed to fall on the black body through a hole in the roof of the dark room. Assuming that there is no change in the ambient temperature of the room, which of the following statement(s) is/are correct?
The quantity of radiation absorbed by the black body in unit time will increase.
Since emissivity $=$ absorptivity, hence the quantity of radiation emitted by black body in unit time will increase.
Black body radiates more energy in unit time in the visible spectrum.
The reflected energy in unit time by the black body remains the same.
In an insulated vessel, 0.05 kg steam at 373 K and 0.45 kg of ice at 253 K are mixed. Then, find the final temperature of the mixture.
Explanation:
$ 0.05 \mathrm{~kg} \text { steam at } 373 \mathrm{~K} \xrightarrow{\mathrm{Q}_1}0.05 \mathrm{~kg} \text { water at } 373 \mathrm{~K} \text {. } $
$ 0.05 \mathrm{~kg} \text { water at } 373 \mathrm{~K} \xrightarrow{\mathrm{Q}_2} 0.05 \mathrm{~kg} \text { water at } 273 \mathrm{~K}$
$ 0.45 \mathrm{~kg} \text { ice at } 253 \mathrm{~K} \xrightarrow{\mathrm{Q}_3} 0.45 \mathrm{~kg} \text { ice at } 273 \mathrm{~K} $
$ 0.45 \mathrm{~kg} \text { ice at } 273 \mathrm{~K} \xrightarrow{\mathrm{Q}_4} 0.45 \mathrm{~kg} \text { water at } 273 \mathrm{~K}$
$ \begin{aligned} &\begin{aligned} & \Rightarrow \mathrm{Q}_1=m \mathrm{~L}=50(540)=27000 \mathrm{cal}=27 \mathrm{kcal} (\mathrm{Q}=m \mathrm{~L}) \\ & \mathrm{Q}_2=m s \Delta t=(50)(1)(100)=500 \mathrm{cal}=5 \mathrm{kcal} \\ & \mathrm{Q}_3=m s \Delta t=(4.50)(0.5)(20)=4500 \mathrm{cal}=4.5 \mathrm{kcal} \\ & \mathrm{Q}_4=(m \mathrm{~L})=450 \times 580=36000 \mathrm{cal}=36 \mathrm{kcal} \,\, [fusion]\end{aligned}\\ &\text { } \end{aligned} $
Since, $Q_1+Q_2>Q_3$ but $Q_1+Q_2 Therefore temperature of mixture $=273 \mathrm{~K}$ (or $0^{\circ} \mathrm{C}$ ) Method II Heat lost by steam to covert into $0^{\circ} \mathrm{C}$ water $ \begin{gathered} \mathrm{H}_{\mathrm{L}}=0.05 \times 540+0.05 \times 10 \times 1 \\ {\left[\mathrm{Q}=\mathrm{H}_{\mathrm{L}}=m \mathrm{~L}+m s \Delta t\right]} \\ \mathrm{H}_{\mathrm{L}}=27+5=32 \mathrm{kcal} \end{gathered} $ Heat required by ice to change into $0^{\circ} \mathrm{C}$ water. $ \begin{aligned} \mathrm{H}_{\mathrm{g}} & =450(20) \frac{1}{2}+450 \times 80 \\ & =4500+36000=40500 \mathrm{cal} \\ & =40.5 \mathrm{kcal} \end{aligned} $ $\Rightarrow$ To convert ice, we have $450 \times \frac{1}{2}=225 \mathrm{cal}$. But we need 32000 cal. Therefore, ice will remain as ice. Hence final temperature is $0^{\circ} \mathrm{C}$.
Heat given to the processes is positive. Match Column I with Column II:
| Column I | Column II | ||
|---|---|---|---|
| (A) | JK | (P) | $ \Delta W>0 $ |
| (B) | KL | (Q) | $ \Delta \mathrm{Q}<0 $ |
| (C) | LM | (R) | $ \Delta \mathrm{W}<0 $ |
| (D) | MJ | (S) | $ \Delta Q>0 $ |
$ [\mathrm{A} \rightarrow(\mathrm{Q}) ; \mathrm{B} \rightarrow(\mathrm{~S}) ; \mathrm{C} \rightarrow(\mathrm{Q}) ; \mathrm{D} \rightarrow( \mathrm{R})]$
$ [\mathrm{A} \rightarrow(\mathrm{Q}) ; \mathrm{B} \rightarrow(\mathrm{P}) ; \mathrm{C} \rightarrow(\mathrm{~S}) ; \mathrm{D} \rightarrow(\mathrm{Q})]$
$ [\mathrm{A} \rightarrow(\mathrm{Q}) ; \mathrm{B} \rightarrow(\mathrm{P}, \mathrm{~S}) ; \mathrm{C} \rightarrow(\mathrm{~S}) ; \mathrm{D} \rightarrow(\mathrm{Q}, \mathrm{R})] $
$ [\mathrm{A} \rightarrow(\mathrm{Q}) ; \mathrm{B} \rightarrow(\mathrm{S}) ; \mathrm{C} \rightarrow(\mathrm{S}) ; \mathrm{D} \rightarrow( \mathrm{R})]$
A cylinder of mass $1 \mathrm{~kg}$ is given heat of $20000 \mathrm{~J}$ at atmospheric pressure. If initially temperature of cylinder is $20^{\circ} \mathrm{C}$, find
(A) The final temperature of the cylinder;
(B) The work done by the cylinder;
(C) The change in internal energy of the cylinder.
Given :
The specific heat of cylinder
$=400 \mathrm{~J} \mathrm{~kg}^{-1 \circ} \mathrm{C}^{-1}$
Coefficient of volume expansion
$=9 \times 10^{-5}{ }^{\circ} \mathrm{C}^{-1} \text {; }$
Atmospheric pressure $=10^{5} \mathrm{~N} / \mathrm{m}^{2}$ Density of cylinder $=9000 \mathrm{~kg} / \mathrm{m}^{3}$ )