iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
For a gas CP $-$ CV = R in a state P and CP $-$ CV = 1.10 R in a state Q, TP and TQ are the temperatures in two different states P and Q respectively. Then
A.
TP = TQ
B.
TP < TQ
C.
TP = 0.9 TQ
D.
TP > TQ
Correct Answer: D
Explanation:
CP $-$ CV = R for ideal gas and gas behaves as ideal gas at high temperature, so TP > TQ
2021
Q502
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A monoatomic ideal gas, initially at temperature T1 is enclosed in a cylinder fitted with a frictionless piston. The gas is allowed to expand adiabatically to a temperature T2 by releasing the piston suddenly. If l1 and l2 are the lengths of the gas column, before and after the expansion respectively, then the value of ${{{T_1}} \over {{T_2}}}$ will be :
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Two different metal bodies A and B of equal mass are heated at a uniform rate under similar conditions. The variation of temperature of the bodies is graphically represented as shown in the figure. The ratio of specific heat capacities is :
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
What will be the average value of energy for a monoatomic gas in thermal equilibrium at temperature T?
A.
${3 \over 2}{k_B}T$
B.
${k_B}T$
C.
${2 \over 3}{k_B}T$
D.
${1 \over 2}{k_B}T$
Correct Answer: A
Explanation:
For a monoatomic ideal gas, the average kinetic energy per molecule is determined by the equipartition theorem. This theorem states that the energy is equally distributed among all the available degrees of freedom.
A monoatomic gas has three translational degrees of freedom, corresponding to motion in the x, y, and z directions. Each degree of freedom contributes an average energy of $\frac{1}{2} k_BT$, where $k_B$ is the Boltzmann constant and $T$ is the absolute temperature.
So for a monoatomic gas with three translational degrees of freedom, the average energy per molecule is: $\frac{3}{2} k_BT.$
2021
Q505
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Which of the following graphs represent the behavior of an ideal gas? Symbols have their usual meaning.
A.
B.
C.
D.
Correct Answer: C
Explanation:
PV = nRT
PV $\propto$ T
Straight line with positive slope (nR)
2021
Q506
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The correct relation between the degrees of freedom f and the ratio of specific heat $\gamma$ is :
A.
$f = {2 \over {\gamma - 1}}$
B.
$f = {2 \over {\gamma + 1}}$
C.
$f = {{\gamma + 1} \over 2}$
D.
$f = {1 \over {\gamma + 1}}$
Correct Answer: A
Explanation:
$\gamma = 1 + {2 \over f}$
$ \Rightarrow $ $f = {2 \over {\gamma - 1}}$
2021
Q507
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Consider a mixture of gas molecule of types A, B and C having masses mA < mB < mC. The ratio of their root mean square speeds at normal temperature and pressure is :
where, m = molar mass of the gas in kilograms per mole,
R = molar gas constant,
and T = temperature in kelvin.
According to question,
mA < mB < mC
From Eq. (i),
${v_{rms}} \propto {1 \over {\sqrt m }}$
$\therefore$ We can write,
vA > vB > vC or ${1 \over {{v_A}}} < {1 \over {{v_B}}} < {1 \over {{v_C}}}$
2021
Q508
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The amount of heat needed to raise the temperature of 4 moles of rigid diatomic gas from 0$^\circ$ C to 50$^\circ$ C when no work is done is ___________. (R is the universal gas constant).
A.
500 R
B.
250 R
C.
750 R
D.
175 R
Correct Answer: A
Explanation:
According to first law of thermodynamics,
$\Delta$Q = $\Delta$U + $\Delta$W ..... (i)
where, $\Delta$Q = quantity of heat energy supplied to the system, $\Delta$U = change in the internal energy of a closed system and $\Delta$W = work done by the system on its surroundings.
CV = specific heat capacity at constant volume for diatomic gas = ${{5R} \over 2}$
$\Delta$T = change in temperature = (50 $-$ 0) = 50$^\circ$C
n = number of moles = 4
$\Rightarrow$ $\Delta$Q = nCV$\Delta$T
= $4 \times {{5R} \over 2} \times (50)$ = 500 R = 500 R
2021
Q509
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The entropy of any system is given by $S = {\alpha ^2}\beta \ln \left[ {{{\mu kR} \over {J{\beta ^2}}} + 3} \right]$ where $\alpha$ and $\beta$ are the constants. $\mu$, J, k and R are no. of moles, mechanical equivalent of heat, Boltzmann constant and gas constant respectively. [Take $S = {{dQ} \over T}$] Choose the incorrect option from the following :
So, from Eqs. (iii) and (viii), we can say that $\alpha$ and k have different dimensions.
2021
Q510
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Consider a sample of oxygen behaving like an ideal gas. At 300 K, the ratio of root mean square (rms) velocity to the average velocity of gas molecule would be :
(Molecular weight of oxygen is 32g/mol; R = 8.3 J K$-$1 mol$-$1)
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
An ideal gas in a cylinder is separated by a piston in such a way that the entropy of one part is S1 and that of the other part is S2. Given that S1 > S2. If the piston is removed then the total entropy of the system will be :
A.
S1 $-$ S2
B.
${{{S_1}} \over {{S_2}}}$
C.
S1 $\times$ S2
D.
S1 + S2
Correct Answer: D
Explanation:
for gas 1, S1 = ${f \over 2}{n_1}R$
for gas 2, S2 = ${f \over 2}{n_2}R$
after removal of piston,
S = ${f \over 2}({n_1} + {n_2})R = {S_1} + {S_2}$
2021
Q513
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The P-V diagram of a diatomic ideal gas system going under cyclic process as shown in figure. The work done during an adiabatic process CD is (use $\gamma$ = 1.4) :
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
What will be the average value of energy along one degree of freedom for an ideal gas in thermal equilibrium at a temperature T? (kB is Boltzmann constant)
A.
${1 \over 2}{k_B}T$
B.
${2 \over 3}{k_B}T$
C.
${3 \over 2}{k_B}T$
D.
${k_B}T$
Correct Answer: A
Explanation:
Energy associated with each digress of freedom is ${1 \over 2}{k_B}T$.
2021
Q515
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
If one mole of the polyatomic gas is having two vibrational modes and $\beta$ is the ratio of molar specific heats for polyatomic gas $\left( {\beta = {{{C_P}} \over {{C_V}}}} \right)$ then the value of $\beta$ is :
A.
1.02
B.
1.35
C.
1.2
D.
1.25
Correct Answer: C
Explanation:
For polyatomic gas molecule has 3 rotational degrees of freedom,
3 translational degrees of freedom, and 2 vibrational modes.
So, number of vibrational degrees of freedom = 2 $ \times $ 2 = 4
Degree of freedom of polyatomic gas
f = T + R + V
f = 3 + 3 + 4 = 10
$\beta = 1 + {2 \over f} = 1 + {2 \over 10}$
$\beta = {{12} \over 10} = 1.2$
2021
Q516
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Which one is the correct option for the two different thermodynamic processes?
A.
(a) only
B.
(c) and (d)
C.
(b) and (c)
D.
(c) and (a)
Correct Answer: B
Explanation:
Isothermal process means constant temperature which is only possible in graph (c) & (d) for adiabatic process
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A polyatomic ideal gas has 24 vibrational modes. What is the value of $\gamma$?
A.
1.37
B.
1.30
C.
1.03
D.
10.3
Correct Answer: C
Explanation:
f = 3T + 3R + 24V
= 30
$\gamma$ = 1 + ${2 \over f}$
$\gamma$ = 1 + ${2 \over 30}$
= 1.066
Nearest Ans. = 1.03
2021
Q518
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Two ideal polyatomic gases at temperatures T1 and T2 are mixed so that there is no loss of energy. If F1 and F2, m1 and m2, n1 and n2 be the degrees of freedom, masses, number of molecules of the first and second gas respectively, the temperature of mixture of these two gases is :
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Two identical metal wires of thermal conductivities K1 and K2 respectively are connected in series. The effective thermal conductivity of the combination is :
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A Carnot's engine working between 400 K and 800 K has a work output of 1200 J per cycle. The amount of heat energy supplied to the engine from the source in each cycle is :
A.
2400 J
B.
1600 J
C.
1800 J
D.
3200 J
Correct Answer: A
Explanation:
$\eta = 1 - {1 \over 2}$
$\eta = {1 \over 2}$
${W \over Q} = \eta $
${{1200} \over Q} = {1 \over 2}$
$Q = 2400J$
2021
Q521
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Calculate the value of mean free path ($\lambda$) for oxygen molecules at temperature 27$^\circ$C and pressure 1.01 $\times$ 105 Pa. Assume the molecular diameter 0.3 nm and the gas is ideal. (k = 1.38 $\times$ 10$-$23 JK$-$1)
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A bimetallic strip consists of metals A and B. It is mounted rigidly as shown. The metal A has higher coefficient of expansion compared to that of metal B. When the bimetallic strip is placed in a cold bath, it will :
A.
Neither bend nor shrink
B.
Bend towards the left
C.
Not bend but shrink
D.
Bend towards the right
Correct Answer: B
Explanation:
Given, ${\alpha _A} > {\alpha _B}$
$ \therefore $ $\Delta {L_A} > \Delta {L_B}$
So, A will contract more than B, so it will bend towards
left.
2021
Q523
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
In thermodynamics, heat and work are :
A.
Path functions
B.
Point functions
C.
Extensive thermodynamics state variables
D.
Intensive thermodynamic state variables
Correct Answer: A
Explanation:
Heat and work are path function.
Heat and work depends on the path taken to reach the final state from initial state.
2021
Q524
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The volume V of an enclosure contains a mixture of three gases, 16 g of oxygen, 28 g of nitrogen and 44 g of carbon dioxide at absolute temperature T. Consider R as universal gas constant. The pressure of the mixture of gases is :
A.
${{3RT} \over V}$
B.
${{4RT} \over V}$
C.
${{88RT} \over V}$
D.
${5 \over 2}{{RT} \over V}$
Correct Answer: D
Explanation:
No. of moles of O2 :
n1 = ${{16} \over {32}}$ = 0.5 mole
No. of moles of N2 :
n2 = ${{28} \over {28}}$ = 1 mole
No. of moles of CO2 :
n3 = ${{44} \over {44}}$ = 1 mole
Total no. of moles in container : n = n1 + n2 + n3
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The internal energy (U), pressure (P) and volume (V) of an ideal gas are related as U $=$ 3PV + 4. The gas is :
A.
either monoatomic or diatomic.
B.
monoatomic only.
C.
polyatomic only.
D.
diatomic only.
Correct Answer: C
Explanation:
U = 3PV + 4
$ \Rightarrow $ ${{nf} \over 2}$RT = 3PV + 4
$ \Rightarrow $ ${{f} \over 2}$PV = 3PV + 4
$ \Rightarrow $ f = 6 + ${8 \over {PV}}$
Since degree of freedom is more than 6 therefore gas is polyatomic.
2021
Q526
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The temperature $\theta$ at the junction of two insulating sheets, having thermal resistances R1 and R2 as well as top and bottom temperatures $\theta$1 and $\theta$2 (as shown in figure) is given by :
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
If one mole of an ideal gas at (P1, V1) is allowed to expand reversibly and isothermally (A to B) its pressure is reduced to one-half of the original pressure (see figure). This is followed by a constant volume cooling till its pressure is reduced to one-fourth of the initial value (B $ \to $ C). Then it is restored to its initial state by a reversible adiabatic compression (C to A). The net workdone by the gas is equal to :
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
On the basis of kinetic theory of gases, the gas exerts pressure because its molecules :
A.
continuously lose their energy till it reaches wall.
B.
are attracted by the walls of container.
C.
suffer change in momentum when impinge on the walls of container.
D.
continuously stick to the walls of container.
Correct Answer: C
Explanation:
On the basis of kinetic theory of gases, the gas exerts pressure
because its molecules contain uniform speed, random motion and
perform elastic collision with each other, as well as with the walls of
container. As a result of which gaseous molecules suffer change in
momentum when impinge on the walls of container
2021
Q533
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Match List I with List II.
List I
List II
(a)
Isothermal
(i)
Pressure constant
(b)
Isochoric
(ii)
Temperature constant
(c)
Adiabatic
(iii)
Volume constant
(d)
Isobaric
(iv)
Heat content is constant
Choose the correct answer from the options given below :
1.
(a) - (ii), (b) - (iii), (c) - (iv), (d) - (i)
2.
(a) - (ii), (b) - (iv), (c) - (iii), (d) - (i)
3.
(a) - (iii), (b) - (ii), (c) - (i), (d) - (iv)
4.
(a) - (i), (b) - (iii), (c) - (ii), (d) - (iv)
Correct Answer: 1
Explanation:
We know that, in isothermal process, $\Delta$T = 0
In isochoric process, $\Delta$V = 0
In adiabatic process, $\Delta$Q = 0
In isobaric process, $\Delta$p = 0
So, the correct match is,
A $\to$ 2, B $\to$ 3, C $\to$ 4, D $\to$ 1
2021
Q534
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
n mole of a perfect gas undergoes a cyclic process ABCA (see figure) consisting of the following processes.
A $ \to $ B : Isothermal expansion at temperature T so that the volume is doubled from V1 to V2 = 2V1 and pressure charges from P1 to P2
B $ \to $ C : Isobaric compression at pressure P2 to initial volume V1.
C $ \to $ A : Isochoric change leading to change of pressure from P2 to P1.
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
Each side of a box made of metal sheet in cubic shape is 'a' at room temperature 'T', the coefficient of linear expansion of the metal sheet is '$\alpha$'. The metal sheet is heated uniformly, by a small temperature $\Delta$T, so that its new temperature is T + $\Delta$T. Calculate the increase in the volume of the metal box.
A.
3a3$\alpha$$\Delta$T
B.
4$\pi$a3$\alpha$$\Delta$T
C.
${{4 \over 3}}$$\pi$a3$\alpha$$\Delta$T
D.
4a3$\alpha$$\Delta$T
Correct Answer: A
Explanation:
We know that, $\gamma = 3\alpha $ .... (i)
where, $\alpha$ is the coefficient of linear expansion and $\gamma$ is the coefficient of volume expansion.
$\Delta V = 3{a^3}\alpha \Delta T$ [ $\because$ volume of cube = a3 ]
2021
Q536
JEE Mains
Numerical
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The temperature of 3.00 mol of an ideal diatomic gas is increased by 40.0$^\circ$C without changing the pressure of the gas. The molecules in the gas rotate but do not oscillate. If the ratio of change in internal energy of the gas to the amount of workdone by the gas is ${x \over {10}}$. Then the value of x (round off to the nearest integer) is ___________. (Given R = 8.31 J mol$-$1 K$-$1)
Correct Answer: 25
Explanation:
Given, the number of diatomic moles, n = 3 mol
The increase in temperature of the diatomic mole,
$\Delta$T = 40$^\circ$C
Now, the degree of freedom
f = linear + rotational + no oscillation
f = 3 + 2 + 0 $\Rightarrow$ f = 5
Change in internal energy,
$\Delta$U = nCv$\Delta$T .... (i)
where, ${C_v} = {f \over 2}R = {5 \over 2}R$
Substituting the value in Eq. (i), we get
$\Delta U = {{5R} \over 2}nR\Delta T$
Now, work done by the gas for isobaric process,
$W = p\Delta V = nR\Delta T$
The ratio of the change in internal energy to the work done by the gas,
Comparing with given equation, ${{\Delta U} \over W} = {x \over {10}}$
The value of the x = 25.
2021
Q537
JEE Mains
Numerical
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The average translational kinetic energy of N2 gas molecules at .............$^\circ$C becomes equal to the K.E. of an electron accelerated from rest through a potential difference of 0.1 volt. (Given kB = 1.38 $\times$ 10$-$23 J/K) (Fill the nearest integer).
Correct Answer: 500
Explanation:
Given, the average translational kinetic energy of dinitrogen (N2) = Kinetic energy of an electron .... (i)
Translational kinetic energy of dinitrogen (N2)
$KE = {3 \over 2}{K_B}T$
Here, T = temperature of the gas,
and KB = Boltzmann constant.
Kinetic energy of an electron = eV
Given, the potential differential of an electron, V = 0.1 V
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A sample of gas with $\gamma$ = 1.5 is taken through an adiabatic process in which the volume is compressed from 1200 cm3 to 300 cm3. If the initial pressure is 200 kPa. The absolute value of the workdone by the gas in the process = _____________ J.
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A heat engine operates between a cold reservoir at temperature T2 = 400 K and a hot reservoir at temperature T1. It takes 300 J of heat from the hot reservoir and delivers 240 J of heat to the cold reservoir in a cycle. The minimum temperature of the hot reservoir has to be ______________ K.
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A rod CD of thermal resistance 10.0 KW$-$1 is joined at the middle of an identical rod AB as shown in figure. The end A, B and D are maintained at 200$^\circ$C, 100$^\circ$C and 125$^\circ$C respectively. The heat current in CD is P watt. The value of P is ................. .
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A system consists of two types of gas molecules A and B having same number density 2 $\times$ 1025/m3. The diameter of A and B are 10 $\mathop A\limits^o $ and 5 $\mathop A\limits^o $ respectively. They suffer collision at room temperature. The ratio of average distance covered by the molecule A to that of B between two successive collision is ____________ $\times$ 10$-$2
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The area of cross-section of a railway track is 0.01 m2. The temperature variation is 10$^\circ$C. Coefficient of liner expansion of material of track is 10$-$5/$^\circ$C. The energy stored per meter in the track is ____________ J/m.
(Young's modulus of material of track is 1011 Nm$-$2)
Correct Answer: 05
Explanation:
As the tracks won't be allowed to expand linearly, the rise in temperature would lead to developing thermal stress in track.
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
One mole of an ideal gas at 27$^\circ$ is taken from A to B as shown in the given PV indicator diagram. The work done by the system will be _________ $\times$ 10$-$1 J. [Given : R = 8.3 J/mole K, ln2 = 0.6931] (Round off to the nearest integer)
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
For an ideal heat engine, the temperature of the source is 127$^\circ$C. In order to have 60% efficiency the temperature of the sink should be ___________$^\circ$C. (Round off to the Nearest Integer)
Correct Answer: -113
Explanation:
Given, temperature of source, TH = 127$^\circ$C
= 273 + 127 = 400 K
Efficiencies, $\eta $ = 60% = 0.6
The efficiency of Carnot (ideal) heat engine is given by
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
1 mole of rigid diatomic gas performs a work of ${Q \over 5}$ when heat Q is supplied to it. The molar heat capacity of the gas during this transformation is ${xR \over 8}$. The value of x is _________. [R = universal gas constant]
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
The volume V of a given mass of monoatomic gas changes with temperature T according to the relation $V = K{T^{{2 \over 3}}}$. The workdone when temperature changes by 90K will be xR. The value of x is _________. [R = universal gas constant]
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A container is divided into two chambers by a partition. The volume of first chamber is 4.5 litre and second chamber is 5.5 litre. The first chamber contain 3.0 moles of gas at pressure 2.0 atm and second chamber contain 4.0 moles of gas at pressure 3.0 atm. After the partition is removed and the mixture attains equilibrium, then, the common equilibrium pressure existing in the mixture is x $\times$ 10$-$1 atm. Value of x is ________.
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A reversible heat engine converts one-fourth of the heat input into work. When the temperature of the sink is reduced by 52K, its efficiency is doubled. The temperature in Kelvin of the source will be __________.
iCON Education HYD, 79930 92826, 73309 7282610 Mar 2026
A monoatomic gas of mass 4.0 u is kept in an insulated container. Container is moving with velocity 30 m/s. If container is suddenly stopped then change in temperature of the gas (R = gas constant) is ${x \over {3R}}$. Value of x is ___________.
Correct Answer: 3600
Explanation:
To find the change in temperature of a monoatomic gas when the container it is in is suddenly stopped, we can follow these steps:
Relationship Between Kinetic Energy and Internal Energy Change:
The kinetic energy lost by the container when it stops is converted into the internal energy of the gas:
$ \Delta KE = \Delta U $
Expression for Internal Energy Change:
The change in internal energy can be expressed in terms of the change in temperature:
$ \Delta U = n C_v \Delta T $
where $ n $ is the number of moles, $ C_v $ is the molar heat capacity at constant volume, and $ \Delta T $ is the change in temperature.
Using the Kinetic Energy Formula for the Change:
For a monoatomic gas, the molar heat capacity at constant volume $ C_v $ is $\frac{3R}{2}$. Thus, we equate the kinetic energy to the change in internal energy:
$ \frac{1}{2} m v^2 = \frac{3}{2} n R \Delta T $
Solving for $\Delta T$:
Rearrange the equation to solve for the change in temperature:
$ \Delta T = \frac{m v^2}{3 n R} $
Substituting Given Values:
Here, mass $ m = 4 $ u, velocity $ v = 30 $ m/s, and the number of moles $ n = 1 $. Substitute these into the equation: