This is a common method to prepare hydrogenperoxide
2022
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2022 (Online) 27th June Morning Shift
BeCl2 reacts with LiAlH4 to give :
A.
Be + Li[AlCl4] + H2
B.
Be + AlH3 + LiCl + HCl
C.
BeH2 + LiCl + AlCl3
D.
BeH2 + Li[AlCl4]
Correct Answer: C
Explanation:
2BeCl2 + LiAlH4 $ \to $ 2 BeH2 + LiCl + AlCl3
The above reaction using LiAlH4 is an important preparation method for production of hydrides.
2022
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2022 (Online) 26th June Evening Shift
s-block element which cannot be qualitatively confirmed by the flame test is :
A.
Li
B.
Na
C.
Rb
D.
Be
Correct Answer: D
Explanation:
Beryllium does not give flame test because of its
small size and high ionization energy the energy of
flame is not sufficient to excite the electrons to
higher energy level.
2022
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2022 (Online) 26th June Morning Shift
$\mathrm{NaOH}$ is crystallised from the remaining part of electrolyte.
2022
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2022 (Online) 24th June Evening Shift
Which one of the following compounds is used as a chemical in certain type of fire extinguishers?
A.
Baking soda
B.
Soda ash
C.
Washing soda
D.
Caustic soda
Correct Answer: A
Explanation:
Baking soda $\left(\mathrm{NaHCO}_{3}\right)$ is used in certain type of fire extinguishers because it decomposes at high temperature to produce $\mathrm{CO}_{2}$ which extinguishes fire
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 27th July Evening Shift
Match List - I with List - II :
List - I
List - II
(a)
Li
(i)
photoelectric cell
(b)
Na
(ii)
absorbent of $C{O_2}$
(c)
K
(iii)
coolant in fast breeder nuclear reactor
(d)
Cs
(iv)
treatment of cancer
(v)
bearings for motor engines
Choose the correct answer from the options given below :
A.
(a) - (v), (b) - (i), (c) - (ii), (d) - (iv)
B.
(a) - (v), (b) - (ii), (c) - (iv), (d) - (i)
C.
(a) - (iv), (b) - (iii), (c) - (i), (d) - (ii)
D.
(a) - (v), (b) - (iii), (c) - (ii), (d) - (i)
Correct Answer: D
Explanation:
Li makes alloy with Lead to make white metal bearings for motor engines
Liquid Na metal is used s coolant in fast breeder nuclear reactor
K is a very absorbent of CO2
Cs is used in making photoelectric cell
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 27th July Morning Shift
Given below are two statements : One is labelled as Assertion A and the other labelled as Reason R.
Assertion A : Lithium halides are some what covalent in nature.
Reason R : Lithium posses high polarisation capability.
In the light of the above statements, choose the most appropriate answer from the options given below :
A.
A is true but R is false
B.
A is false but R is true
C.
Both A and R are true but R is NOT the correct explanation of A
D.
Both A and R are true and R is the correct explanation of A
Correct Answer: D
Explanation:
Lithium due to small size has very high polarization capability and thus increases covalent nature of Halides.
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 25th July Evening Shift
Match List I with List II :
List-I Elements
List-II Properties
(a)
Li
(i)
Poor water solubility of ${I^ - }$ salt
(b)
Na
(ii)
Most abundant element in cell fluid
(c)
K
(iii)
Bicarbonate salt used in fire extinguisher
(d)
Cs
(iv)
Carbonate salt decomposes easily on heating
Choose the correct answer from the options given below :
A.
(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
B.
(a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)
C.
(a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
D.
(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
Correct Answer: A
Explanation:
(a) CsI salt is poor water soluble due to it's low hydration energy
(b) NaHCO3 is used in fire extinguisher
(c) K is most abundant element in cell fluid
(d) Li2CO3 decomposes easily due to high covalent character caused by small size Li+ cation.
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 25th July Morning Shift
Given below are two statements :
Statement I : None of the alkaline earth metal hydroxides dissolve in alkali.
Statement II : Solubility of alkaline earth metal hydroxides in water increases down the group.
In the light of the above statements, choose the most appropriate answer from the options given below :
A.
Statement I is correct but Statement II is incorrect.
B.
Statement I is incorrect but Statement II is correct.
C.
Statement I and Statement II both are incorrect.
D.
Statement I and Statement II both are correct.
Correct Answer: B
Explanation:
Statement - I is incorrect
Be(OH)2 dissolve in alkali due to it's amphoteric nature.
Statement - II is correct
Solubility of alkaline earth metal hydroxide in water increases down the group due to rapid decreases in lattice energy as compared to hydration energy.
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 22th July Evening Shift
Match List-I with List-II
List-I (Elements)
List-II (Properties)
(a)
Ba
(i)
Organic solvent soluble compounds
(b)
Ca
(ii)
Outer electronic configuration $6{s^2}$
(c)
Li
(iii)
Oxalate insoluble in water
(d)
Na
(iv)
Formation of very strong monoacidic base
Choose the correct answer from the options given below :
A.
(a)-(ii), (b)-(iii), (c)-(i) and (d)-(iv)
B.
(a)-(iv), (b)-(i), (c)-(ii) and (d)-(iii)
C.
(a)-(iii), (b)-(ii), (c)-(iv) and (d)-(i)
D.
(a)-(i), (b)-(iv), (c)-(ii) and (d)-(iii)
Correct Answer: A
Explanation:
(a) 'Ba' having outer electronic configuration 6s2
(b) CaC2O4 is water insoluble
(c) 'Li' is soluble in organic solvents
(d) NaOH is strong Monoacidic base among given
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 20th July Morning Shift
The set in which compounds have different nature is :
A.
B(OH)3 and H3PO3
B.
B(OH)3 and Al(OH)3
C.
NaOH and Ca(OH)2
D.
Be(OH)2 and Al(OH)3
Correct Answer: B
Explanation:
(A) Both are acidic in nature.
B(OH)3 is orthoboric acid. It can accept a pair of electrons from Lewis bases and hence, act as Lewis acid.
H3PO3 is (phosphorus acid) diprotic acid as it readily ionises two protons.
(B) B(OH)3 is acidic and Al(OH)3 is amphoteric in nature.
(C) Both NaOH and Ca(OH)2 are basic hydroxides.
(D) Both Be(OH)2 and Al(OH)3 are amphoteric hydroxides.
Hence, only B(OH)3 and Al(OH)3 have different nature.
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 20th July Morning Shift
A s-block element (M) reacts with oxygen to form an oxide of the formula MO2. The oxide is pale yellow in colour and paramagnetic. The element (M) is :
A.
Mg
B.
Na
C.
Ca
D.
K
Correct Answer: D
Explanation:
The element (M) is potassium (K). It reacts with O2 to form KO2, which is paramagnetic in nature. All other elements form oxides or peroxides which are diamagnetic in nature.
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 18th March Evening Shift
Match List - I with List - II :
List - I
List - II
(a)
Be
(i)
treatment of cancer
(b)
Mg
(ii)
extraction of metals
(c)
Ca
(iii)
incendiary bombs and signals
(d)
Ra
(iv)
windows of X-ray tubes
(v)
bearings for motor engines
Choose the most appropriate answer from the option given below :
A.
(a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
B.
(a)-(iii), (b)-(iv), (c)-(v), (d)-(ii)
C.
(a)-(iii), (b)-(iv), (c)-(ii), (d)-(v)
D.
(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
Correct Answer: D
Explanation:
Beryllium is used in the manufacture of alloys. Metallic beryllium is used for making windows of
X-ray tubes. Radium salts are used in radiotherapy, for example, in the treatment of cancer. Magnesium
(powder and ribbon) is used in flash powders and bulbs, incendiary bombs and signals. Calcium is used
in the extraction of metals from oxides which are difficult to reduce with carbon.
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 18th March Morning Shift
Match List - I with List - II
List - I
List - II
(a)
$Ca{(OCl)_2}$
(i)
Antacid
(b)
$CaS{O_4}.{1 \over 2}{H_2}O$
(ii)
Cement
(c)
$CaO$
(iii)
Bleach
(d)
$CaC{O_3}$
(iv)
Plaster of paris
Choose the most appropriate answer from the options given below :
A.
(a) - (i), (b) - (iv), (c) - (iii), (d) - (ii)
B.
(a) - (iii), (b) - (ii), (c) - (iv), (d) - (i)
C.
(a) - (iii), (b) - (iv), (c) - (ii), (d) - (i)
D.
(a) - (iii), (b) - (ii), (c) - (i), (d) - (iv)
Correct Answer: C
Explanation:
CaSO4${1 \over 2}$ H2O - Plaster of Paris
Ca(OCl)2 - Bleaching agent
CaO is used in cement
CaCO3 is used as an Antacid
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 17th March Evening Shift
The set of elements that differ in mutual relationship from those of the other sets is :
A.
Li - Na
B.
Be - Al
C.
B - Si
D.
Li - Mg
Correct Answer: A
Explanation:
Li–Mg, B–Si, Be–Al show diagonal
relationship but Li and Na do not show
diagonal relationship as both belongs to same
group and not placed diagonally.
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 17th March Evening Shift
One of the by-products formed during the recovery of NH3 from Solvay process is :
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 17th March Morning Shift
The correct order of conductivity of ions in water is :
A.
K+ > Na+ > Cs+ > Rb+
B.
Cs+ > Rb+ > K+ > Na+
C.
Na+ > K+ > Rb+ > Cs+
D.
Rb+ > Na+ > K+ > Li+
Correct Answer: B
Explanation:
As the size of gaseous ion decreases, it get
more hydrated in water and hence, the size of
aqueous ion increases. When this bulky ion
move in solution, it experience greater
resistance and hence lower conductivity.
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 16th March Morning Shift
Given below are two statements :
Statement I : Both CaCl2 . 6H2O and MgCl2 . 8H2O undergo dehydration on heating.
Statement II : BeO is amphoteric whereas the oxides of other elements in the same group are acidic.
In the light of the above statements, choose the correct answer from the options given below :
Among alkaline earth metal BeO is amphoteric & rest are basic oxide
2021
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2021 (Online) 24th February Evening Shift
Match List - I with List - II.
List I (Salt)
List II (Flame colour wavelength)
(a)
LiCl
(i)
455.5 nm
(b)
NaCl
(ii)
670.8 nm
(c)
RbCl
(iii)
780.0 nm
(d)
CsCl
(iv)
589.2 nm
Choose the correct answer from the options given below :
A.
(a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)
B.
(a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
C.
(a)-(i), (b)-(iv), (c)-(ii), (d)-(iii)
D.
(a)-(ii), (b)-(iv), (c)-(iii), (d)-(i)
Correct Answer: D
Explanation:
Alkali metal
Colour (Flame)
$\lambda $ (nm)
Li
Crimson red
670.8
Na
Yellow
589.2
Rb
Red, violet
780.0
Cs
Blue
455.5
Alkali metals have very low value of ionisation energy as compared to other metals. So, alkali metals easily get excited and impart colour to flame.
Hence, Rb is most excited and having high value of wavelength in all alkali metals.
2020
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2020 (Online) 6th September Evening Slot
Match the following compounds (Column-I) with
their uses (Column-II) :
S.No.
Column-I
S.No.
Column-II
(I)
Ca(OH)2
(A)
casts of statues
(II)
NaCl
(B)
white wash
(III)
CaSO4, ${1 \over 2}$H2O
(C)
antacid
(IV)
CaCO3
(D)
washing soda
preparation
A.
(I)-(B), (II)-(C), (III)-(D), (IV)-(A)
B.
(I)-(B), (II)-(D), (III)-(A), (IV)-(C)
C.
(I)-(C), (II)-(D), (III)-(B), (IV)-(A)
D.
(I)-(D), (II)-(A), (III)-(C), (IV)-(B)
Correct Answer: B
Explanation:
(I) Ca(OH)2
is used in white wash due to its disinfectant nature.
(II) NaCl is used in preparation of washing soda(Na2CO3).
(1) 2NH3
+ H2O + CO2 $ \to $ (NH4
)2CO3 (2) (NH4
)2CO3
+ H2O + CO2 $ \to $ 2NH4HCO3 (3) NH4HCO3
+ NaCl $ \to $ NH4Cl + NaHCO3 (4) 2NaHCO3 $ \to $ Na2CO3
+ CO2
+ H2O
(III) CaSO4.${1 \over 2}$H2O (Plaster of Paris) Used for making casts of
statues.
(IV) CaCO3 is used as an Antacid.
2020
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2020 (Online) 6th September Morning Slot
Among the sulphates of alkaline earth metals,
the solubilities of BeSO4 and MgSO4 in water,
respectively, are :
A.
poor and poor
B.
poor and high
C.
high and poor
D.
high and high
Correct Answer: D
Explanation:
Order of solubility of sulphate of Alkaline earth metals
BeSO4
> MgSO4
> CaSO4
> SrSO4
> BaSO4
The greater hydration enthalpies of
Be2+ and Mg2+ ions dominate over their lattice
enthalpies and therefore their sulphates are
highly soluble.
2020
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2020 (Online) 4th September Evening Slot
An alkaline earth metal ‘M’ readily forms water
soluble sulphate and water insoluble hydroxide.
Its oxide MO is very stable to heat and does not
have rock-salt structure. M is :
A.
Ca
B.
Mg
C.
Sr
D.
Be
Correct Answer: D
Explanation:
BeSO4
is water soluble.
Be(OH)2
is water insoluble.
BeO is stable to heat.
2020
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2020 (Online) 4th September Morning Slot
On combustion of Li, Na and K in excess of air,
the major oxides formed, respectively, are :
A.
Li2O, Na2O2 and K2O
B.
Li2O2, Na2O2 and K2O2
C.
Li2O, Na2O2 and KO2
D.
Li2O, Na2O and K2O2
Correct Answer: C
Explanation:
4Li + O2 $ \to $ 2Li2O
2Na + O2 $ \to $ Na2O2
K + O2 $ \to $ KO2
2020
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2020 (Online) 2nd September Evening Slot
Two elements A and B have similar chemical
properties. They don’t form solid
hydrogencarbonates, but react with nitrogen to
form nitrides. A and B, respectively, are :
A.
Li and Mg
B.
Cs and Ba
C.
Na and Rb
D.
Na and Ca
Correct Answer: A
Explanation:
Solid hydrogencarbonates are not formed
by lithium and magnesium.
– 6Li + N2 $ \to $ 2Li3N
– 3Mg + N2 $ \to $ Mg3N2
2020
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2020 (Online) 2nd September Morning Slot
The metal mainly used in devising
photoelectric cells is :
A.
Na
B.
Rb
C.
Li
D.
Cs
Correct Answer: D
Explanation:
Cs has least work function value because of
less electronegativity thats why it is used in
photoelectric cells.
2020
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2020 (Online) 9th January Evening Slot
Among the statements (a)-(d) the correct ones
are :
(a) Lithium has the highest hydration enthalpy
among the alkali metals.
(b) Lithium chloride is insoluble in pyridine.
(c) Lithium cannot form ethynide upon its
reaction with ethyne.
(d) Both lithium and magnesium react slowly
with H2O.
A.
(b) and (c) only
B.
(a) and (d) only
C.
(a), (b) and (d) only
D.
(a), (c) and (d) only
Correct Answer: D
Explanation:
Lithium has highest hydration enthalpy among
alkali metals due to its small size.
LiCl is soluble in pyridine because LiCl have
more covalent character.
Li does not form ethynide with ethyne.
Both Li and Mg reacts slowly with H2O.
2020
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2020 (Online) 8th January Morning Slot
Ionic potential of Li is high that is why on thermal demoposition of nitrate form of Li will give oxide of Li and NO2 and O2.
2019
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2019 (Online) 12th April Morning Slot
The correct sequence of thermal stability of the following carbonates is :
A.
BaCO3 < SrCO3 < CaCO3 < MgCO3
B.
MgCO3 < CaCO3 < SrCO3 < BaCO3
C.
BaCO3 < CaCO3 < SrCO3 < MgCO3
D.
MgCO3 < SrCO3 < CaCO3 < BaCO3
Correct Answer: B
Explanation:
Stability of alkaline earth metal carbonates
increases down the group as size of cation increases ans polarization decreases down the group :
MgCO3 < CaCO3 < SrCO3 < BaCO3
2019
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2019 (Online) 10th April Evening Slot
A hydrated solid X on heating initially gives a monohydrated compound Y. Y upon heating above 373 K leads
to an anhydrous white powder Z. X and Z, respectively, are :
A.
Baking soda and dead burnt plaster.
B.
Washing soda and soda ash
C.
Washing soda and dead burnt plaster.
D.
Baking soda and soda as.
Correct Answer: B
Explanation:
2019
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2019 (Online) 10th April Morning Slot
The alloy used in the construction of aircrafts is :
A.
Mg – Zn
B.
Mg – Al
C.
Mg – Mn
D.
Mg – Sn
Correct Answer: B
Explanation:
An alloy of Mg and Al called magnalium is used
in manufacturing of aircraft due to its light
weight and high strength.
2019
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2019 (Online) 9th April Evening Slot
The structures of beryllium chloride in the solid
state and vapour, phase, respectively,are :
A.
chain and chain
B.
dimeric and chain
C.
chain and dimeric
D.
dimeric and dimeric
Correct Answer: C
Explanation:
BeCl2 in vapour phase exist as dimer [(BeCl2)2] (below
1200 K temperature).
BeCl2 in solid state has chain structure[(BeCl2)n].
2019
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2019 (Online) 9th April Morning Slot
Magnisium powder burns in air to give :
A.
MgO and Mg3N2
B.
MgO only
C.
Mg(NO3)2 and Mg3N2
D.
MgO and Mg(NO3)2
Correct Answer: A
Explanation:
Mg burn in air and produces a mixture of
nitride and oxide.
So, Mg3N2 and MgO are formed.
2019
JEE Mains
MCQ
iCON Education HYD, 79930 92826, 73309 72826JEE Main 2019 (Online) 8th April Morning Slot
The correct order of hydration enthapies of alkali metal ions is :