Surface Chemistry

116 Questions
2021 JEE Mains MCQ
JEE Main 2021 (Online) 26th August Morning Shift
Which one of the following is correct for the adsorption of a gas at a given temperature on a solid surface?
A.
$\Delta$H > 0, $\Delta$S > 0
B.
$\Delta$H > 0, $\Delta$S < 0
C.
$\Delta$H < 0, $\Delta$S < 0
D.
$\Delta$H < 0, $\Delta$S > 0
2021 JEE Mains MCQ
JEE Main 2021 (Online) 25th July Evening Shift
Match List I with List II :

List-I
Example of colloids
List - II
Classification
(a) Cheese (i) dispersion of liquid in liquid
(b) Pumice stone (ii) dispersion of liquid in gas
(c) Hair cream (iii) dispersion of gas in solid
(d) Cloud (iv) dispersion of liquid in solid

Choose the most appropriate answer from the options given below
A.
(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
B.
(a)-(iv), (b)-(i), (c)-(iii), (d)-(ii)
C.
(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
D.
(a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
2021 JEE Mains MCQ
JEE Main 2021 (Online) 22th July Evening Shift
When silver nitrate solution is added to potassium iodide solution then the sol produced is :
A.
AgI / I$-$
B.
AgI / Ag+
C.
KI / NO$_3^ - $
D.
AgNO3 / NO$_3^ - $
2021 JEE Mains MCQ
JEE Main 2021 (Online) 20th July Morning Shift
The conditions given below are in the context of observing Tyndall effect in colloidal solutions :

(A) The diameter of the colloidal particles is comparable to the wavelength of light used.

(B) The diameter of the colloidal particles is much smaller than the wavelength of light used.

(C) The diameter of the colloidal particles is much larger than the wavelength of light used.

(D) The refractive indices of the dispersed phase and the dispersion medium are comparable.

(E) The dispersed phase has a very different refractive index from the dispersion medium.

Choose the most appropriate conditions from the options given below :
A.
(A) and (E) only
B.
(C) and (D) only
C.
(A) and (D) only
D.
(B) and (E) only
2021 JEE Mains MCQ
JEE Main 2021 (Online) 18th March Evening Shift
The charges on the colloidal CdS sol and TiO2 sol are, respectively :
A.
positive and positive
B.
positive and negative
C.
negative and negative
D.
negative and positive
2021 JEE Mains MCQ
JEE Main 2021 (Online) 17th March Evening Shift
For the coagulation of a negative sol, the species below, that has the highest flocculating power is :
A.
Na+
B.
Ba2+
C.
PO$_4^{3 - }$
D.
SO$_4^{2 - }$
2021 JEE Mains MCQ
JEE Main 2021 (Online) 17th March Morning Shift
A colloidal system consisting of a gas dispersed in a solid is called a/an :
A.
foam
B.
aerosol
C.
solid sol
D.
gel
2021 JEE Mains MCQ
JEE Main 2021 (Online) 16th March Evening Shift
The INCORRECT statements below regarding colloidal solutions is :
A.
The flocculating power of Al3+ is more than that of Na+.
B.
A colloidal solutions shows Brownian motion of colloidal particles.
C.
An ordinary filter paper can stop the flow of colloidal particles.
D.
A colloidal solutions shows colligative properties.
2021 JEE Mains MCQ
JEE Main 2021 (Online) 26th February Evening Shift
The nature of charge on resulting colloidal particles when FeCl3 is added to excess of hot water is :
A.
neutral
B.
sometimes positive and sometimes negative
C.
positive
D.
negative
2021 JEE Mains MCQ
JEE Main 2021 (Online) 25th February Evening Shift
Which one of the following statements is FALSE for hydrophilic sols?
A.
They do not require electrolytes for stability.
B.
The sols cannot be easily coagulated.
C.
These sols are reversible in nature.
D.
Their viscosity is of the order of that of H2O.
2021 JEE Mains MCQ
JEE Main 2021 (Online) 25th February Morning Shift
In Freundlich adsorption isotherm at moderate pressure, the extent of adsorption $\left( {{x \over m}} \right)$ is directly proportional to Px. The value of x is :
A.
$\infty $
B.
zero
C.
1
D.
${{1 \over n}}$
2021 JEE Mains MCQ
JEE Main 2021 (Online) 24th February Evening Shift
Most suitable salt which can be used for efficient clotting of blood will be :
A.
Mg(HCO3)2
B.
NaHCO3
C.
FeCl3
D.
FeSO4
2021 JEE Mains MCQ
JEE Main 2021 (Online) 24th February Morning Shift
In Freundlich adsorption isotherm, slope of AB line is :

JEE Main 2021 (Online) 24th February Morning Shift Chemistry - Surface Chemistry Question 66 English
A.
${1 \over n}$ with $\left( {{1 \over n} = 0\,to\,1} \right)$
B.
n with (n, 0.1 to 0.5)
C.
$\log {1 \over n}$ with $\left( {n < 1} \right)$
D.
log n with (n > 1)
2021 JEE Mains Numerical
JEE Main 2021 (Online) 31st August Evening Shift
CH4 is absorbed on 1g charcoal at 0$^\circ$C following the Freundlich adsorpiton isotherm 10.0 mL of CH4 is adsorbed at 100 mm of Hg, whereas 15.0 mL is adsorbed at 200 mm of Hg. The volume of CH4 adsorbed at 300 mm of Hg is 10x mL. The value of x is _________ $\times$ 10-2.

(Nearest integer) [Use log102 = 0.3010, log103 = 0.4771]
2021 JEE Mains Numerical
JEE Main 2021 (Online) 27th July Morning Shift
CO2 gas adsorbs on charcoal following Freundlich adsorption isotherm. For a given amount of charcoal, the mass of CO2 adsorbed becomes 64 times when the pressure of CO2 is doubled. The value of n in the Freundlich isotherm equation is ____________ $\times$ 10$-$2. (Round off to the Nearest Integer)
2021 JEE Mains Numerical
JEE Main 2021 (Online) 20th July Evening Shift
100 ml of 0.0018% (w/v) solution of Cl$-$ ion was the minimum concentration of Cl$-$ required to precipitate a negative sol in one h. The coagulating value of Cl$-$ ion is _________ (Nearest integer)
2020 JEE Mains MCQ
JEE Main 2020 (Online) 6th September Morning Slot
Kraft temperature is the temperature :
A.
below which the aqueous solution of detergents starts freezing.
B.
above which the formation of micelles takes place.
C.
below which the formation of micelles takes place.
D.
above which the aqueous solution of detergents starts boiling.
2020 JEE Mains MCQ
JEE Main 2020 (Online) 5th September Evening Slot
Adsorption of a gas follows Freundlich adsorption isotherm. If x is the mass of the gas adsorbed on mass
m of the adsorbent, the correct plot of ${x \over m}$ versus p is :
A.
JEE Main 2020 (Online) 5th September Evening Slot Chemistry - Surface Chemistry Question 69 English Option 1
B.
JEE Main 2020 (Online) 5th September Evening Slot Chemistry - Surface Chemistry Question 69 English Option 2
C.
JEE Main 2020 (Online) 5th September Evening Slot Chemistry - Surface Chemistry Question 69 English Option 3
D.
JEE Main 2020 (Online) 5th September Evening Slot Chemistry - Surface Chemistry Question 69 English Option 4
2020 JEE Mains MCQ
JEE Main 2020 (Online) 5th September Morning Slot
Identify the correct molecular picture showing that happens at the critical micellar concentration (CMC) of an aqueous solution of a surfactant ( ◍ polar head; ∼ non-polar tail; ● water). JEE Main 2020 (Online) 5th September Morning Slot Chemistry - Surface Chemistry Question 70 English
A.
(C)
B.
(A)
C.
(D)
D.
(B)
2020 JEE Mains MCQ
JEE Main 2020 (Online) 4th September Evening Slot
A sample of red ink (a colloidal suspension) is prepared by mixing eosin dye, egg white, HCHO and water. The component which ensures stability of the ink sample is :
A.
HCHO
B.
Water
C.
Eosin dye
D.
Egg white
2020 JEE Mains MCQ
JEE Main 2020 (Online) 4th September Morning Slot
Match the following :

(i) Foam (a) smoke
(ii) Gel (b) cell fluid
(iii) Aerosol (c) jellies
(iv) Emulsion (d) rubber
(e) froth
(f) Milk
A.
(i)-(e), (ii)-(c), (iii)-(a), (iv)-(f)
B.
(i)-(d), (ii)-(b), (iii)-(a), (iv)-(e)
C.
(i)-(d), (ii)-(b), (iii)-(e), (iv)-(f)
D.
(i)-(b), (ii)-(c), (iii)-(e), (iv)-(d)
2020 JEE Mains MCQ
JEE Main 2020 (Online) 3rd September Evening Slot
An ionic micelle is formed on the addition of :
A.
excess water to liquid JEE Main 2020 (Online) 3rd September Evening Slot Chemistry - Surface Chemistry Question 73 English Option 1
B.
excess water to liquid JEE Main 2020 (Online) 3rd September Evening Slot Chemistry - Surface Chemistry Question 73 English Option 2
C.
liquid diethyl ether to aqueous NaCl solution
D.
sodium stearate to pure toluene
2020 JEE Mains MCQ
JEE Main 2020 (Online) 3rd September Morning Slot
Tyndall effect is observed when:
A.
The diameter of dispersed particles is similar to the wavelenght of light used.
B.
The diameter of dispersed particles is much smaller than the wavelength of light used.
C.
The diameter of dispersed particles is much larger than the wavelength of light used.
D.
The refractive index of dispersed phase is greater than that of the dispersion medium.
2020 JEE Mains MCQ
JEE Main 2020 (Online) 2nd September Evening Slot
Amongst the following statements regarding adsorption, those that are valid are

(a) $\Delta $H becomes less negative as adsorption proceeds
(b) On a given adsorbent, ammonia is adsorbed more than nitrogen gas
(c) On adsorption, the residual force acting along the surface of the adsorbent increases
(d) With increase in temperature, the equilibrium concentration of adsorbate increases
A.
(c) and (d)
B.
(a) and (b)
C.
(d) and (a)
D.
(b) and (c)
2020 JEE Mains MCQ
JEE Main 2020 (Online) 2nd September Morning Slot
Which of the following is used for the preparation of colloids?
A.
Van Arkel Method
B.
Bredig’s Arc Method
C.
Mond Process
D.
Ostwald Process
2020 JEE Mains MCQ
JEE Main 2020 (Online) 9th January Evening Slot
A mixture of gases O2, H2 and CO are taken in a closed vessel containing charcoal. The graph that represents the correct behaviour of pressure with time is :
A.
JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Surface Chemistry Question 78 English Option 1
B.
JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Surface Chemistry Question 78 English Option 2
C.
JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Surface Chemistry Question 78 English Option 3
D.
JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Surface Chemistry Question 78 English Option 4
2020 JEE Mains MCQ
JEE Main 2020 (Online) 8th January Evening Slot
For the following Assertion and Reason, the correct option is
Assertion : For hydrogenation reactions, the catalytic activity increases from Group 5 to Group 11 metals with maximum activity shown by Group 7-9 elements.
Reason : The reactants are most strongly adsorbed on group 7-9 elements.
A.
Both assertion and reason are true and the reason is the correct explanation for the assertion.
B.
The assertion is true, but the reason is false.
C.
Both assertion and reason are true but the reason is not the correct explanation for the assertion.
D.
Both assertion and reason are false.
2020 JEE Mains MCQ
JEE Main 2020 (Online) 8th January Morning Slot
As per Hardy-Schulze formulation, the flocculation values of the following for ferric hydroxide sol are in the order :
A.
AICl3 > K3[Fe(CN)6] > K2CrO4 > KBr = KNO3
B.
K3[Fe(CN)6] < K2CrO4 < KBr = KNO3 = AlCl3
C.
K3[Fe(CN)6] < K2CrO4 < AlCl3 < KBr < KNO3
D.
K3[Fe(CN)6] > AlCl3 > K2CrO4 > KBr > KNO3
2020 JEE Mains Numerical
JEE Main 2020 (Online) 6th September Evening Slot
For Freundlich adsorption isotherm, a plot of log (x/m) (y-axis) and log p (x-axis) gives a straight line. The intercept and slope for the line is 0.4771 and 2, respectively. The mass of gas, adsorbed per gram of adsorbent if the initial pressure is 0.04 atm, is ______ $ \times $ 10–4 g.
(log 3 = 0.4771)
2020 JEE Mains Numerical
JEE Main 2020 (Online) 2nd September Morning Slot
The mass of gas adsorbed, x, per unit mass of adsorbate, m, was measured at various pressures, p. A graph between $\log {x \over m}$ and log p gives a straight line with slope equal to 2 and the intercept equal to 0.4771. The value of ${x \over m}$ at a pressure of 4 atm is :
(Given log 3 = 0.4771)
2019 JEE Mains MCQ
JEE Main 2019 (Online) 12th April Evening Slot
Among the following, the INCORRECT statement about colloids is :
A.
The range of diameters of colloidal particles is between 1 and to 1000 nm
B.
they are larger than small molecules and have high molar mass
C.
They can scatter light
D.
The osmotic pressure of a colloidal solution is of higher order than the true solution at the same concentration.
2019 JEE Mains MCQ
JEE Main 2019 (Online) 12th April Morning Slot
Peptization is a :
A.
process of converting soluble particles to form colloidal solution
B.
process of converting precipitate into colloidal solution
C.
process of bringing colloidal molecule into solution
D.
process of converting a colloidal solution into precipitate
2019 JEE Mains MCQ
JEE Main 2019 (Online) 10th April Evening Slot
The correct option among the following is :
A.
Addition of alum to water makes it unfit for drinking.
B.
Colloidal medicines are more effective because they have small surface area.
C.
Colloidal paraticles in lyophobic sols can be precipitated by electrophoresis.
D.
Brownian motion in colloidal solution is faster if the viscosity of the solution is very high.
2019 JEE Mains MCQ
JEE Main 2019 (Online) 10th April Morning Slot
A gas undergoes physical adsorption on a surface and follows the given Freundlich adsorption isotherm equation

${x \over m} = k{p^{0.5}}$

Adsorption of the gas increase with :
A.
Decrease in p and increase in T
B.
Increase in p and decrease in T
C.
Decrease in p and decrease in T
D.
Increase in p and increase in T
2019 JEE Mains MCQ
JEE Main 2019 (Online) 9th April Morning Slot
Match the catalysts (Column I) with products (Column II).

Column I Column II
(A) V2O5 (i) Polyethylene
(B) TiCl4/Al(Me)3 (ii) ethanal
(C) PdCl2 (iii) H2SO4
(D) Iron Oxide (iv) NH3
A.
(A)-(iii); (B)-(i); (C)-(ii); (D)-(iv)
B.
(A)-(ii); (B)-(iii); (C)-(i); (D)-(iv)
C.
(A)-(iii); (B)-(iv); (C)-(i); (D)-(ii)
D.
(A)-(iv); (B)-(iii); (C)-(ii); (D)-(i)
2019 JEE Mains MCQ
JEE Main 2019 (Online) 9th April Morning Slot
The aerosol is a kind of colloid in which :
A.
solid is dispersed in gas
B.
gas is dispersed in solid
C.
gas is dispersed in liquid
D.
liquid is dispersed in water
2019 JEE Mains MCQ
JEE Main 2019 (Online) 8th April Morning Slot
Adsorption of a gas follows freundlich adosorbed isotherm. x is the mass of the gas adsorbed on mass m of the adsorbent. The plot log $x \over m$ versus log p is shown in the given graph. $x \over m$ is proportional to : JEE Main 2019 (Online) 8th April Morning Slot Chemistry - Surface Chemistry Question 87 English
A.
p2/3
B.
p3
C.
p2
D.
p3/2
2019 JEE Mains MCQ
JEE Main 2019 (Online) 12th January Evening Slot
Among the following the false statement is -
A.
Lyophilic sol can be coagulated by adding an electrote
B.
Tyndall effect can be used to distinguish between a colloidal solution and a true solution
C.
It is possible to cause artificial rain by throwing electrified sand carrying charge opposite to the one on clouds from an aeroplane
D.
Latex is a colloidal solution of rubber particles which are positively charged
2019 JEE Mains MCQ
JEE Main 2019 (Online) 12th January Morning Slot
Given
Gas H2 CH4 CO2 SO2
Critical
Temperature / K
33 190 304 630



On the basis of data given above, predict which of the following gases shows least adsorption on a definite amount of charcoal ?
A.
SO2
B.
CH4
C.
H2
D.
CO2
2019 JEE Mains MCQ
JEE Main 2019 (Online) 11th January Evening Slot
Among the colloids cheese (C), milk (M), and smoke (S), the correct combination of the dispersed phase and dispersion medium, respectively is :
A.
C : liquid in solid ; M : liquid in liquid ; S : solid in gas
B.
C : liquid in solid ; M : liquid in solid ; S : solid in gas
C.
C : solid in liquid ; M : liquid in liquid ; S : gas in solid
D.
C : solid in liqid ; M : solid in liquid ; S : solid in gas
2019 JEE Mains MCQ
JEE Main 2019 (Online) 11th January Morning Slot
An example of solid sol is :
A.
Butter
B.
Hair cream
C.
Gem stones
D.
Paint
2019 JEE Mains MCQ
JEE Main 2019 (Online) 10th January Evening Slot
Haemoglobin and gold sol are examples of :
A.
positively charged sols
B.
negatively charged sols
C.
Positively and negatively charged sols, respectively
D.
negatively and positively charged sols, respectively
2019 JEE Mains MCQ
JEE Main 2019 (Online) 10th January Morning Slot
Which of the following is not an example of heterogenous catalytic reaction?
A.
Ostwald's process
B.
Combustion of coal
C.
Hydrogenation of vegetable oils
D.
Haber's process
2019 JEE Mains MCQ
JEE Main 2019 (Online) 9th January Evening Slot
For coagulation of arsenious sulphate sol, which one of the following salt solution will be most effective ?
A.
BaCl2
B.
AlCl3
C.
NaCl
D.
Na3PO4
2019 JEE Mains MCQ
JEE Main 2019 (Online) 9th January Morning Slot
Adsorption of a gas follows Freundlich adsorption isotherm. In the given plot, x is the mass of the gas adsorbed on mass m of the adsorbent at pressure P. ${x \over m}$ is proportional to :

JEE Main 2019 (Online) 9th January Morning Slot Chemistry - Surface Chemistry Question 95 English
A.
P2
B.
P${^{{1 \over 4}}}$
C.
P${^{{1 \over 2}}}$
D.
P
2018 JEE Mains MCQ
JEE Main 2018 (Online) 16th April Morning Slot
Which one of the following is not a property of physical adsorption?
A.
Higher the pressure, mre the adsorption
B.
Lower the temperature, more the adsorption
C.
Greater the surface area, more the adsorption
D.
Unilayer adsorption ocurs
2018 JEE Mains MCQ
JEE Main 2018 (Online) 15th April Evening Slot
If x gram of gas is adsorbed by m gram of adsorbent at pressure P, the plot of log ${x \over m}$ versus log P is linear. The slope of the plot is :
(n and k are constants and n > 1)
A.
2 k
B.
log k
C.
n
D.
${1 \over n}$
2018 JEE Mains MCQ
JEE Main 2018 (Online) 15th April Morning Slot
Which of the following statements about colloids is False ?
A.
Freezing point of colloidal solution is lower than true solution at same concentration of a solute.
B.
Colloidal particles can pass through ordinary filter paper.
C.
When silver nitrate solution is added to potassium iodide solution, a negatively charged colloidal solution is formed.
D.
When excess of electolyte is added to colloidal solution, colloidal particle will be precipitated.
2017 JEE Mains MCQ
JEE Main 2017 (Online) 9th April Morning Slot
Adsorption of a gas on a surface follows Freundlich adsorption isotherm. Plot of log ${x \over m}$ versus log p gives a straight line with slope equal to 0.5, then:

( ${x \over m}$ is the mass of the gas adsorbed per gram of adsorbent)
A.
Adsorption is independent of pressure.
B.
Adsorption is proportional to the pressure.
C.
Adsorption is proportional to the square root of pressure.
D.
Adsorption is proportional to the square of pressure.
2017 JEE Mains MCQ
JEE Main 2017 (Online) 8th April Morning Slot
Among the following, correct statement is :
A.
Brownian movement is more pronounced for smaller particles than for bigger–particles
B.
Sols of metal sulphides are lyophilic.
C.
Hardy Schulze law states that bigger the size of the ions, the greater is its coagulating power.
D.
One would expect charcoal to adsorb chlorine more than hydrogen sulphide.