NEET
2026
MCQ
In a qualitative analysis, $\mathrm{Bi}^{3+}$ is detected by appearance of precipitate of $\mathrm{BiO}(\mathrm{OH})(\mathrm{s})$. Calculate pH when the following equilibrium exists at 298 K .
$ \mathrm{BiO}(\mathrm{OH})(\mathrm{s}) \rightleftharpoons \mathrm{BiO}^{+}(\mathrm{aq})+\mathrm{OH}^{-}(\mathrm{aq}), \mathrm{K}=4 \times 10^{-10} $
(Given : $\log 2=0.3010$ )
NEET
2026
MCQ
At 298 K , a certain buffer solution contains equal concentrations of $\mathrm{X}^{-}$and $\mathrm{HX}, \mathrm{K}_{\mathrm{b}}$ for $\mathrm{X}^{-}$is $10^{-10}$. What is the pH of this buffer solution?
NEET
2026
MCQ
Phenolphthalein is used as an indicator for the titration of sodium hydroxide solution against a standard solution of oxalic acid. The colour change that is observed at an alkaline pH close to the equivalence point during this titration is:
NEET
2026
MCQ
$ \text { The correct order of solubility of the given salts in water at } 298 \mathrm{~K} \text { is } $
$ \begin{array}{|l|l|} \hline \text { Salt } & \mathbf{K}_{\text {sp }} \text { at } \mathbf{2 9 8} \text { K } \\ \hline \mathrm{AgBr} & 5.0 \times 10^{-13} \\ \hline \mathrm{Zn}(\mathrm{OH})_2 & 1.0 \times 10^{-15} \\ \hline \mathrm{Hg}_2 \mathrm{Cl}_2 & 1.3 \times 10^{-18} \\ \hline \end{array} $
NEET
2025
MCQ
If the molar conductivity $\left(\Lambda_{\mathrm{m}}\right)$ of a $0.050 \mathrm{~mol} \mathrm{~L}^{-1}$ solution of a monobasic weak acid is $90 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$, its extent (degree) of dissociation will be
[Assume $\Lambda_{+}^{\circ}=349.6 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$ and $\Lambda_{-}^{\circ}=50.4 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$.]
NEET
2025
MCQ
Phosphoric acid ionizes in three steps with their ionization constant values $K_{a_1}, K_{a_2}$ and $K_{a_3}$, respectively, while $K$ is the overall ionization constant. Which of the following statements are true?
A. $\quad \log \mathrm{K}=\log \mathrm{K}_{\mathrm{a}_1}+\log \mathrm{K}_{\mathrm{a}_2}+\log \mathrm{K}_{\mathrm{a}_3}$
B. $\mathrm{H}_3 \mathrm{PO}_4$ is a stronger acid than $\mathrm{H}_2 \mathrm{PO}_4^{-}$and $\mathrm{HPO}_4^{2-}$
C. $K_{a_1}>K_{a_2}>K_{a_3}$
D. $K_{a_1}=\frac{K_{a_3}+K_{a_2}}{2}$
Choose the correct answer from the options given below :
NEET
2024
MCQ
Which indicator is used in the titration of sodium hydroxide against oxalic acid and what is the colour change at the end point?
NEET
2024
MCQ
The ratio of solubility of AgCl in 0.1 M KCl solution to the solubility of AgCl in water is:
(Given : Solubility product of AgCl = 10$^{–10}$)
NEET
2023
MCQ
An acidic buffer is prepared by mixing :
NEET
2022
MCQ
0.01 M acetic acid solution is 1% ionised, then pH of this acetic acid solution is :
NEET
2022
MCQ
The pH of the solution containing 50 mL each of 0.10 M sodium acetate and 0.01 M acetic acid is [Given pKa of CH3COOH = 4.57]
NEET
2021
MCQ
The pKb of dimethyl amine and pKa of acetic acid are 3.27 and 4.77 respectively at T (K). The correct option for the pH of dimethyl ammonium acetate solution is :
NEET
2020
MCQ
Find out the solubility of Ni(OH)2 in 0.1M NaOH. Given that the ionic product of Ni(OH)2 is 2 $ \times $ 10-15.
NEET
2019
MCQ
Conjugate base for Bronsted acids H2O and HF are :
NEET
2019
MCQ
pH of a saturated solution of Ca(OH)2 is 9. The solubility product (Ksp) of Ca(OH)2 is :
NEET
2019
MCQ
Which will make basic buffer?
NEET
2018
MCQ
The solubility of BaSO4
in water is
2.42 × 10–3 g L–1 at 298 K. The value of its
solubility product (Ksp) will be (Given molar
mass of BaSO4
= 233 g mol–1)
NEET
2018
MCQ
Following solutions were prepared by mixing
different volumes of NaOH and HCl of different
concentrations :
A. 60 mL ${M \over {10}}$ HCl + 40 mL ${M \over {10}}$ NaOH
B. 55 mL ${M \over {10}}$ HCl + 45 mL ${M \over {10}}$ NaOH
C. 75 mL ${M \over {5}}$ HCl + 25 mL ${M \over {5}}$ NaOH
D. 100 mL ${M \over {10}}$ HCl + 100 mL ${M \over {10}}$ NaOH
pH of which one of them will be equal to 1?
NEET
2017
MCQ
Concentration of the Ag+ ions in a saturated solution of Ag2C2O4 is 2.2 $ \times $ 10$-$4 mol L$-$1. Solubility product of Ag2C2O4 is
NEET
2016
MCQ
Which of the following fluro-compounds is most likely to behave as a Lewis base ?
NEET
2016
MCQ
The solubility of AgCl(s) with solubility product 1.6 $ \times $ 10$-$10 in 0.1 M NaCl solution would be
NEET
2016
MCQ
The percentage of pyridine (C5H5N) that forms pyridinium ion (C5H5N+H) ina 0.10 M aqueous pyridine solution (Kb for C5H5N = 1.7 $ \times $ 10$-$9) is
NEET
2016
MCQ
MY and NY3, two nearly insoluble salts, have the same Ksp values of 6.2 $ \times $ 10$-$13 at room temperature. Which statement would be true in regard to MY and NY3?
NEET
2015
MCQ
What is the pH of the resulting solution when equal volumes of 0.1 M NaOH and 0.01 M HCl are mixed?
NEET
2015
MCQ
Which one of the following pairs of solution is not an acidic buffer ?
NEET
2015
MCQ
The Ksp of Ag2CrO4, AgCl, AgBr and Agl are respectively, 1.1 $ \times $ 10$-$12, 1.8 $ \times $ 10$-$10, 5.0 $ \times $ 10$-$13, 8.3 $ \times $ 10$-$17. Which one of the following salts will precipitate last if AgNO3 solution is added to the solution containing equal moles of NaCl, NaBr, Nal and Na2CrO4?
NEET
2014
MCQ
Which of the following salts will give highest pH in water?
NEET
2013
MCQ
The dissociation constant of weak acid is 1 $ \times $ 10$-$4. In order to prepare a buffer solution with a pH = 5, the [Salt]/[Acid] ratio should be
NEET
2013
MCQ
At 100oC the Kw of water is 55 times its value at 25oC. What will be the pH of neutral solution? (log 55 = 1.74)
NEET
2013
MCQ
The values of Ksp of CaCO3 and CaC2O4 are 4.7 $ \times $ 10$-$9 and 1.3 $ \times $ $-$9 respectively at 25oC. If the mixture of these two is washed with water, what is the concentration of Ca2+ ions in water ?
NEET
2013
MCQ
Accumulation of lactic acid (HC3H5O3), a monobasic acid in tissues leads to pain and a feeling of fatigue. In a 0.10 M aqueous solution, lactic acid is 3.7% dissociates. The value of dissociation constant, Ka, for this acid will be
NEET
2013
MCQ
KMnO4 can be prepared from K2MnO4 as per the reaction,
3MnO42$-$ + 2H2O $\rightleftharpoons$ 2MnO4$-$ + MnO2 + 4OH$-$
The reaction can go to completion by removing OH$-$ ions by adding
NEET
2013
MCQ
Which of these is least likely to act as a lewis base ?
NEET
2012
MCQ
Buffer solutions have constant acidity and alkalinity because
NEET
2012
MCQ
Equimolar solutions of the following substances were prepared separately. Which one of these will record the highest pH value ?
NEET
2012
MCQ
pH of a saturated solution of Ba(OH)2 is 12. The value of solubility product (Ksp) of Ba(OH)2 is
NEET
2011
MCQ
In qualitative analysis, the metals of group I can be separated from other ions by precipitating them as chloride salts. A solution initially contains Ag+ and pb2+ at a concentration of 0.10 M. Aqueous HCl is added to this solution until the Cl$-$ concentration is 0.10 M. What will the concentrations of Ag+ and Pb2+ be at equilibrium ?
(Ksp for AgCl = 1.8 $ \times $ 10$-$10, Ksp for PbCl2 = 1.7 $ \times $ 10$-$5)
NEET
2011
MCQ
Which of the following is least likely to behave as Lewis base?
NEET
2011
MCQ
A buffer solution is prepared in which the concentration of NH3 is 0.30 M and the concentration of NH+4 is 0.20 M. If the equilibrium constant, Kb for NH3 equals 1.8 $ \times $ 10$-$5, what is the pH of this solution? (log 2.7 = 0.43)
NEET
2010
MCQ
What is [H+] in mol/L of a solution that is 0.20 M in CH3COONa and 0.10 M in CH3COOH? Ka for CH3COOH = 1.8 $ \times $ 10$-$5
NEET
2010
MCQ
If pH of a saturated solution of Ba(OH)2 is 12, the value of its Ksp is
NEET
2010
MCQ
In a buffer solution containing equal concentration of B$-$ and HB, the Kb for B$-$ is 10$-$10. The pH of buffer solution is
NEET
2009
MCQ
Which of the following molecules acts as a Lewis acid?
NEET
2009
MCQ
The ionization constant of ammonium hydroxide is 1.77 $ \times $ 10$-$5 at 298 K. Hydrolysis constant of ammonium chloride is
NEET
2009
MCQ
What is the [OH$-$] in the final solution prepared by mixing 20.0 mL of 0.050 M HCl with 30.0 mL of 0.10 M Ba(OH)2?
NEET
2008
MCQ
Equal volumes of three acid solutions of pH 3, 4 and 5 are mixed in a vessel. What will be the H+ ion concentration in the mixture?
NEET
2007
MCQ
A weak acid, HA, has a Ka of 1.00 $ \times $ 10$-$5. If 0.100 mol of this acid is dissolved in one litre of water, the percentage of acid dissociated at equilibrium is closest to
NEET
2007
MCQ
Calculate the pOH of a solution at 25oC that contains 1 $ \times $ 10$-$10 M of hydronium ions, i.e. H3O+.
NEET
2006
MCQ
The hydrogen ion concentration of a 10$-$8 M, HCl aqueous solution at 298 K (Kw = 10$-$14) is
NEET
2006
MCQ
Which of the following pairs constitutes a buffer?
NEET
2005
MCQ
H2S gas when passed through a solution of cations containing HCl precipitates the cations of second group of qualitative analysis but not those belonging to the fourth group. It is because
NEET
2005
MCQ
At 25oC, the dissociation constant of a base, BOH, is 1.0 $ \times $ 10$-$12. The concentration of hydroxyl ions in 0.01 M aqueous solution of the base would be
NEET
2004
MCQ
The rapid change of pH near the stoichiometric point of an acid-base titration is the basis of indicator detection. pH of the solution is related to ratio of the concentrations of the conjugate acid (HIn) and base (In$-$) forms of the indicator by the expression
NEET
2004
MCQ
The solubility product of a sparingly soluble salt AX2 is 3.2 $ \times $ 10$-$11. Its solubility (in moles/L) is
NEET
2003
MCQ
The solubility product of AgI at 25oC is 1.0 $ \times $ 10$-$16 mol2 L$-$2. The solubility of AgI in 10$-$4 N solution of KI at 25oC is approximately (in mol L$-$1
NEET
2002
MCQ
Solution of 0.1 N NH4OH and 0.1 N NH4Cl has pH 9.25. Then find out pKb of NH4OH
NEET
2002
MCQ
Solubility of MX2 type electrolytes is 0.5 $ \times $ 10$-$4 mole/lit., then find out Ksp of electrolytes.
NEET
2002
MCQ
Which has highest pH?
NEET
2001
MCQ
Solubility of M2S salt is 3.5 $ \times $ 10$-$6 then find out solubility product.
NEET
2001
MCQ
In HS$-$, I$-$, R $-$ NH2, NH3 order of proton accepting tendency will be
NEET
2001
MCQ
Ionisation constant of CH3COOH is 1.7 $ \times $ 10$-$5 and concentration of H+ ions is 3.4 $ \times $ 10$-$4. Then find out initial concentration of CH3COOH molecules.
NEET
2001
MCQ
Correct relation between dissociation constants of a dibasic acid is
NEET
2000
MCQ
Conjugate acid of NH2$-$ is
NEET
2000
MCQ
Which statement is wrong about pH and H+?